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Why are aliphatic carboxylic acids stron...

Why are aliphatic carboxylic acids stronger than phenols?

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The aliphatic carboxylic acids are stronger acids than phenols. The difference in the relative acidic strengths can be understood if we compare the resonance hybrids of carboxylate ion and phenoxide ion.

The electron charge in the carboxylate ion is more dispersed in comparison to the phenate ion since there are two electronegative oxygen atoms in carboxylate ion as compared to only one oxygen atom in phenate ion. In other words, the carboxylate ion is relatively more stable as compared to phenate ion. Thus, the release of `H^(+)` ion from carboxylic acid is comparatively easier or it behaves as a stronger acid than phenol.
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MBD -HARYANA BOARD-ALDEHYDES, KETONES AND CARBOXYLIC ACIDS-SHORT ANSWER TYPE QUESTIONS
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  2. Lower members of aldehydes are soluble in water where as the higher m...

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  3. Point out the difference between addition reactions in alkenes and ca...

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  4. (a) Discuss briefly the following reactions : (i) Gattermann Koch re...

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  5. Why is it necessary to control the pH during the addition of ammonia ...

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  6. Identify A from the following: (i) C(6)H(5)COCH(3) overset(A)to C(6)...

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  7. Benzophenone does not react with NaHSO(3). Explain.

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  8. Why are aliphatic carboxylic acids stronger than phenols?

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  9. Explain the term ozonolysis with an example.

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  10. What information can be obtained on the structure of alkene on ozonol...

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  11. By means of suitable chemical test, how will you distinguish acetophen...

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  12. Give two tests for aldehyde.

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  13. By means of a suitable chemical test, how will you distinguish an alde...

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  14. Which type of aldehydes undergo aldol condensation. Give an example.

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  15. Write a note on Clemmensen reduction.

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  16. What is formalin ? Give its use.

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  17. What happens when formaldehyde reacts with ammonia ?

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  18. How are aldehydes distinguished from ketones using Tollen's and Fehli...

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  19. Write the IUPAC names of : (i) CH(3)underset(Br)underset(|)CH-COOH (...

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  20. Write the IUPAC names of the following: (i) CH(3)-CH(CH(3))-CHO ...

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