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Assertion : The root mean square velocit...

Assertion : The root mean square velocity of an ideal gas at constant pressure varies with density as `1//sqrtd`.
Reason : Average kinetic energy of a gas is directly proportional to the absolute temperature.

A

Assertion and reason both are correct statements and reason is correct explanation for assertion.

B

Assertion and reason both are correct statements but reason is not correct explanation for assertion.

C

Assertion is correct statement but reason is wrong statement.

D

Assertion is wrong statement but reason is correct statement.

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the given assertion and reason, we will break down the concepts step by step. ### Step 1: Understanding the Assertion The assertion states that the root mean square velocity (Vrms) of an ideal gas at constant pressure varies with density (d) as \( \frac{1}{\sqrt{d}} \). **Explanation:** - The formula for root mean square velocity is given by: \[ V_{rms} = \sqrt{\frac{3RT}{M}} \] where \( R \) is the universal gas constant, \( T \) is the absolute temperature, and \( M \) is the molar mass of the gas. - At constant pressure, we can use the ideal gas law \( PV = nRT \) or \( P = \frac{nRT}{V} \). - Rearranging gives us \( RT = PV \). - Substituting this back into the Vrms equation leads us to express Vrms in terms of density: \[ V_{rms} = \sqrt{\frac{3P}{\frac{M}{V}}} = \sqrt{\frac{3P}{d}} \] where \( d = \frac{M}{V} \) is the density. - This shows that \( V_{rms} \) varies as \( \frac{1}{\sqrt{d}} \). ### Step 2: Understanding the Reason The reason states that the average kinetic energy of a gas is directly proportional to the absolute temperature. **Explanation:** - The average kinetic energy (KE) of a gas is given by: \[ KE = \frac{3}{2}RT \] - This indicates that the average kinetic energy is directly proportional to the absolute temperature \( T \). - Therefore, this statement is also true. ### Step 3: Analyzing the Relationship Now, we need to analyze the relationship between the assertion and the reason. - Both the assertion and the reason are true statements. - However, the reason does not provide a correct explanation for the assertion. The assertion is about the relationship between Vrms and density, while the reason discusses kinetic energy and temperature. ### Conclusion - The assertion is correct. - The reason is correct. - However, the reason does not explain the assertion. Thus, the answer to the question is: **Assertion is correct, Reason is correct, but Reason is not the correct explanation for Assertion.**
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