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Why are BeSO(4) and MgSO(4) readily solu...

Why are `BeSO_(4)` and `MgSO_(4)` readily soluble in water while `CaSO_(4),SrSO_(4)` and `BaSO_(4)` are insoluble?

Text Solution

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The hydration enthalpies of `BeSO_(4) and MgSO_(4)` are quite high because of small size of `Be^(2+) and Mg^(2+)` ions. These hydration enthalpy values are higher than their corresponding lattice enthalpies and therefore, `BeSO_4` and `MgSO_(4)` are highly soluble in water. However, hydration enthalpies of `CaSO_4, SrSO_4 and BaSO_(4)` are not very high as compared to lattice enthalpies and hence these are insoluble in water.
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