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Assertion : K, Rb and Cs can also form s...

Assertion : K, Rb and Cs can also form superoxides.
Reason : Their ionic radii increase in the order `Cs^(+) lt Rb^(+) lt K^(+)`.

A

Assertion and reason both are correct statements and reason is correct explanation for assertion.

B

Assertion and reason both are correct statements but reason is not correct explanation for assertion.

C

Assertion is correct statement but reason is wrong statement.

D

Assertion is wrong statement but reason is correct statement

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AI Generated Solution

The correct Answer is:
To solve the question regarding the assertion and reason related to the formation of superoxides by potassium (K), rubidium (Rb), and cesium (Cs), we can follow these steps: ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that K, Rb, and Cs can form superoxides. - Superoxides are compounds that contain the superoxide ion (O₂⁻). - In group 1 of the periodic table, larger alkali metal cations (like K⁺, Rb⁺, and Cs⁺) can stabilize larger anions, such as the superoxide ion. 2. **Analyzing the Reason**: - The reason provided states that the ionic radii increase in the order Cs⁺ < Rb⁺ < K⁺. - However, this statement is incorrect. As we move down the group in the periodic table, the ionic radius increases due to the addition of electron shells. Therefore, the correct order should be K⁺ > Rb⁺ > Cs⁺. 3. **Conclusion on Assertion and Reason**: - Since the assertion is true (K, Rb, and Cs can form superoxides) and the reason is false (the order of ionic radii is incorrect), we conclude that the assertion is correct while the reason is incorrect. 4. **Final Answer**: - The correct answer is that the assertion is true and the reason is false.
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MODERN PUBLICATION-S-BLOCK ELEMENTS ( ALKALI AND ALKALINE EARTH METALS ) -Revision Exercises (Objective/Very Short answer questions(Fill in the blanks) )
  1. Li reacts directly with nitrogen to from lithium nitride.

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  2. Solvay process is used for the manufacturing of

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  3. Alkali metals readily dissolve in liquid ammonia to give blue coloured...

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  4. The ionisation energy of alkali metals decreases from Li to Cs bacause

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  5. Which of the following compound(s) will impart a golden yellow colour ...

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  6. Plaster of paris is

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  7. Assertion (A): Lithium chloride is predominantly covalent compound. ...

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  8. Assertion (A): Na(2)SO(4) is soluble in water while BaSO(4) is insolub...

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  9. Al(OH)(3) is amphoteric is nature. Al-O and O-H bonds can be borken ...

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  10. Assertion: Barium is not required for normal biological function in hu...

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  11. Assertion: Li resembles with Mg in properties Reason: Li^(+) has alm...

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  12. Assertion (A): Alkali metals impart colour to the flame. Reason (R )...

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  13. Assertion (A): Sulphur is estimates as BaSO(4) and not as MgSO(4). R...

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  14. Statement -1: Of the chloride of alkaline earth metals BeCl(2) is cova...

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  15. Be forms [BeF(4)]^(2-), but Al forms [AiF(6)]^(3-). Reason (R ): Be...

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  16. Assertion : K, Rb and Cs can also form superoxides. Reason : Their ...

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  17. Assertion (A): CuCI is more covalent than NaCI. Reason (R ): Na^(o+)...

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  18. Assertion : Be gives characteristic flame colouration. Reason : Ion...

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  19. Assertion (A) Beryllium carbonate is kept in the atomsphere of carbon ...

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  20. Assertion (A) The carbonate of lithium decomposes easily on heating to...

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