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When an alkali metal dissolves in liquid...

When an alkali metal dissolves in liquid ammonia the solution can acquire different colours. Explain the reasons for this type of colour change.

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Alkali metals oxide are obtained by combustion of the metals.Although Na normally gives Na_2O_2 ,it will take up further oxygen at elevated pressure and temperature to form NaO_2 .The per and superoxides of the heavier alkalies can also be prepared by passing stoichiometric amounts of oxygen into their solution in liquid ammonia. The different alkali metal oxides can be distinguished by reaction with water.The superoxides reacts with CO_2 and give oxygen gas.The stability of per and superoxides is based upon that larger cation can stablise larger anion, due to larger lattice energy. Alkali metals dissolve in liquid ammonia.Dilute solutions are dark blue in colour but as the concentration increases above 3M, the colour changes to copper bronze and the solution acquires the metallic lusture due to the formation of metal ions clusters.The solutions of alkali metals in liquid ammonia are good conductors of electricity due to the presence of ammoniated cations and ammoniated electrons.However, the conductivity decreases as the concentrations increases, since ammoniated electrons and ammoniated cation associate. Select the correct choice for alkali metal oxides.

Alkali metals oxide are obtained by combustion of the metals.Although Na normally gives Na_2O_2 ,it will take up further oxygen at elevated pressure and temperature to form NaO_2 .The per and superoxides of the heavier alkalies can also be prepared by passing stoichiometric amounts of oxygen into their solution in liquid ammonia. The different alkali metal oxides can be distinguished by reaction with water.The superoxides reacts with CO_2 and give oxygen gas.The stability of per and superoxides is based upon that larger cation can stablise larger anion, due to larger lattice energy. Alkali metals dissolve in liquid ammonia.Dilute solutions are dark blue in colour but as the concentration increases above 3M, the colour changes to copper bronze and the solution acquires the metallic lusture due to the formation of metal ions clusters.The solutions of alkali metals in liquid ammonia are good conductors of electricity due to the presence of ammoniated cations and ammoniated electrons.However, the conductivity decreases as the concentrations increases, since ammoniated electrons and ammoniated cation associate. KO_2 is used in oxygen cylinders in space and submarines because it :

When sodium metal is dissolved in liquid ammonia, blue colour solution is formed. The blue colour is due to

The metal that dissolves in liquid ammonia, giving a dark blue coloured solution is

MODERN PUBLICATION-S-BLOCK ELEMENTS ( ALKALI AND ALKALINE EARTH METALS ) -Revision Exercises (Objective/Very Short answer questions( Short Answer Questions ) )
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  3. What happens when (i) calcium nitrate is heated (ii) chlorine re...

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  4. Lime is used for

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  5. The alkali metals follow the noble gases in their atomic structure. Wh...

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  6. Give the chemistry of extraction of magnesium by Down's process?

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  7. a. Describe one method of manufacture of caustic soda. b. What happe...

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  8. Commerical aluminium always contains some magnesium, name two such all...

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  9. List four properties of Li in which it differs from rest of the family...

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  10. List four properties of Be in which Be differs from rest of the family...

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  11. Describe two important uses of each of the following: (a) casutic so...

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  12. Lithium forms monoide, sodium gives peroxide while the rest of the alk...

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  13. Discuss the various reactions that occur in the Solvay process

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  15. ANOMALOUS BEHAVIOUR OF BERYLLIUM

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  16. What are s-block elements?

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  17. When an alkali metal dissolves in liquid ammonia the solution can acqu...

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  18. Discuss the trend of the following (i) Thermal stability of carbonat...

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  19. What is the structure of BeCI(2) molecule in gaseous and solid state?

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  20. All compounds of alkali metals are easily soluble in water but lithium...

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