Pyrolusite ore on oxidation with `KCIO_(3)//KNO_(3)` in basic medium produces dark green coloured compound `(A)`, which on electrolysis produces a purple coloured compound `(B)`. The purple coloured rhombic prisms. It shows different reactions in different mediums.
Excess of compounds (B) on heating with conc. `H_(2)SO_(4)` gives an explosive oil (C ), which on heating decomposes to gives another compound (D ) along with oxygen.
Identify (D).

Pyrolusite ore on oxidation with KCIO_(3)//KNO_(3) in basic medium produces dark green coloured compound (A) , which on electrolysis produces a purple coloured compound (B) . The purple coloured rhombic prisms. It shows different reactions in different mediums. Excess of compounds (B) on heating with conc. H_(2)SO_(4) gives an explosive oil (C ), which on heating decomposes to gives another compound (D ) along with oxygen. On passing CO_(2) in the solution of (A), a purple coloured solution along with brown ppt is observed.

Pyrolusite ore on oxidation with KCIO_(3)//KNO_(3) in basic medium produces dark green coloured compound (A) , which on electrolysis produces a purple coloured compound (B) . The purple coloured rhombic prisms. It shows different reactions in different mediums. Excess of compounds (B) on heating with conc. H_(2)SO_(4) gives an explosive oil (C ), which on heating decomposes to gives another compound (D ) along with oxygen. The nature of compound (C ) is :

Pyrolusite ore on oxidation with KCIO_(3)//KNO_(3) in basic medium produces dark green coloured compound (A) , which on electrolysis produces a purple coloured compound (B) . The purple coloured rhombic prisms. It shows different reactions in different mediums. Excess of compounds (B) on heating with conc. H_(2)SO_(4) gives an explosive oil (C ), which on heating decomposes to gives another compound (D ) along with oxygen. The nature of compound (C ) is :

Pyrolusite ore on oxidation with KCIO_(3)//KNO_(3) in basic medium produces dark green coloured compound (A) , which on electrolysis produces a purple coloured compound (B) . The purple coloured rhombic prisms. It shows different reactions in different mediums. Excess of compounds (B) on heating with conc. H_(2)SO_(4) gives an explosive oil (C ), which on heating decomposes to gives another compound (D ) along with oxygen. When (D) reacts with PbO_(2)//HNO_(3) it produces a purple // pink coloured compound (E). Identify (E)

Pyrolusite ore on oxidation with KCIO_(3)//KNO_(3) in basic medium produces dark green coloured compound (A) , which on electrolysis produces a purple coloured compound (B) . The purple coloured rhombic prisms. It shows different reactions in different mediums. Excess of compounds (B) on heating with conc. H_(2)SO_(4) gives an explosive oil (C ), which on heating decomposes to gives another compound (D ) along with oxygen. Red coloured oxide (M) whose cation has pseudo inert electronic configuration reacts with compound (B) in acidic medium gives another oxide (N) which is black in colour. When sulphate of its metal is reacted with K_(4)[Fe(CN)_(6) it produces chocolate brown ppt. Select the correct statement.

Pyrolusite ore on oxidation with KClO_(3) / KNO_(3) in basic medium produces dark green coloured compound "(A)," which on electrolysis produces a purple coloured compound (B).The purple coloured compound can be crystallised to deep purple rhombic prisms.It shows different reactions in different mediums.Excess of compound (B) on heating with conc. H_(2)SO_(4) gives an explosive oil (C),which on heating decomposes to gives another compound (D) along with oxygen.Identify (D)

An compound (A) which undergo halogorm reaction give compound (B) on reduction . Compound (B) on dehydration with conc. H_(2)SO_(4) gives compound ( C ) which forms secondary butylbromide with HBr. Identify (A).

A blackish brown coloured solid 'A' when fused with alkali metal hydroxides in presence of air, produces a dark green coloured compound 'B' which on electrolytic oxidation in alkaline medium gives a dark purple coloured compound 'C' Identify A, B and C and write the reactions involved.