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An organic compound A with molecular for...

An organic compound A with molecular formula `C_(9)H_(10)O` gives positive DNP and iodoform tests. It does not reduce. Tollen's reagent or Fehling reagent and does not decolourless bromine water or Bayer's reagent. On drastic oxidation with chronic acid, compound A gives a carboxylic acid having molecular formula `C_(7)H_(6)O_(2)`. Deduce the structur eof organic compound A and write all the chemical reactions involved.

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An organic compound [A] with molecular formula C_(9)H_(10)O forms an arage-red precipitate [B] with 2,4 DNP reagent. Compound [A] gives yellow precipiatate [C] on heating wihth iodine in the presence of soedium hydroxide along with a colourless compound [D]. The compound [A] does not reduce Tollen's reagent or Fehling's solution nor does it decolourise bromine water or Baeyer's reagent. On drastic oxidation with chromic acid, compound [A] gives a crboxylic acid [E] having molecular formula C_(7)H_(6)O_(2) . Deduce the strcutres of the organic compounds [A] to [E].

An organic compound (A) with molecular formula C_(8)H_(8)O forms an orange-red precipitate with 2,4-DNP reagent and gives yellow precipitate on heating with iodine in the presence of sodium hydroxide. It neither reduces Tollens’ or Fehlings’ reagent, nor does it decolourise bromine water or Baeyer’s reagent. On drastic oxidation with chromic acid, it gives a carboxylic acid (B) having molecular formula C_(7)H_(6)O_(2) . Identify the compounds (A) and (B) and explain the reactions involved.

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