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Explain the geometry and magnetic nature...

Explain the geometry and magnetic nature of the following complex ions on the basis nof valence bond theory
`(Cr(NH_(3))_(6)]^(3+)`
(ii) `[Fe(CN)_(6))]^(4)`
(iii) `[FeF_(5)]^(3-)`
(iv) `[MnCl_(4))]^(2)`
(V) `[Mncl(4)]^(2-)`
(vi) `[Cu(NH_(3)_(4)]^(2)`

Text Solution

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Octahedral, paramagnetic
(ii) octahedral, diamagnetic
(iii) octahedral, paramagnetic
(iv) tetrahedral, paramagnetic
(V) square planar, diamagnetic
(vi) square planar, paramagnetic
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FIITJEE-TRANSITION ELEMENTS & COORDINATION COMPOUNDS-MATCHIG LIST TYPE QUESTIONS
  1. Explain the geometry and magnetic nature of the following complex ions...

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