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A : In alkene, hydroboration oxidation p...

A : In alkene, hydroboration oxidation process is an example of pericyclic reaction.
R : `BH_(3)` forms the cyclic transition state with double bond.

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion, then mark (1).

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark (2)

C

if Assertion is true statement but Reason is false, then mark (3)

D

If both Assertion and Reason are false statements, then mark (4)

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the given statements regarding the hydroboration-oxidation process in alkenes and determine if the assertion (A) and reason (R) are correct, we can follow these steps: ### Step 1: Understand the Assertion (A) The assertion states that the hydroboration-oxidation process in alkenes is an example of a pericyclic reaction. ### Step 2: Define Pericyclic Reactions Pericyclic reactions are a class of reactions that occur through a cyclic transition state and involve a concerted process, meaning that bonds are formed and broken in a single step without intermediates. ### Step 3: Analyze the Hydroboration-Oxidation Process In the hydroboration-oxidation process: 1. An alkene reacts with diborane (B2H6) or borane (BH3). 2. The boron atom adds across the double bond of the alkene. 3. This reaction forms a cyclic transition state where the boron interacts with the double bond of the alkene. ### Step 4: Understand the Reason (R) The reason states that BH3 forms a cyclic transition state with the double bond. This is indeed true, as the addition of borane to the alkene involves the formation of a cyclic arrangement where the boron atom and the alkene's π electrons interact. ### Step 5: Conclusion Since the assertion (A) correctly identifies the hydroboration-oxidation process as a pericyclic reaction, and the reason (R) correctly explains why this is the case by stating that BH3 forms a cyclic transition state with the double bond, we can conclude that both statements are true and that the reason is a correct explanation of the assertion. ### Final Answer Both the assertion (A) and reason (R) are true, and the reason is the correct explanation of the assertion. ---
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What is meant by hydroboration-oxidation reaction ? Illustrate it with an example.

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Addition OF HOH to Alkenes, Hydroboration-Oxidation Reaction(HBO Reaction Complete)

Borane is an electron deficient compound. It has only six valence eletons, so the boron atom lacks an octet. Acquiring an octet is the driving force for the unusual bonding structure found in boron compounds. As an electron deficient compound, BH_(3) is a strong electrophile, capable of adding to a double bond. This hydroboration of double bond is though to oC Cur in one step, with the boron atom adding to the less highly substituted end of the double bond. In transition state, the boron atom withdraws electrons from the pi bond and the carbon at theother end of the double bond acquires a partial positive charge. This positive charge is more stable on the more highly subsituted carbon atom. The second step is the oxidation of boron atom, removing it from carbon and replacing it with hydroxyl group by using H_(2)O_(2)//OH^(bar(..)) . The simultaneous addition of boron and hydrogen to the double bond leads to a syn addition. Oxidation of the trialkyl borane replaces boron with a hydroxyl group in the same stereochemical position. Thus, hydroboration of alkenen is an example of steropecific reaction, in which different steroisomers of starting compounds react to give different steroisomers of the product. CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-CH=CH_(2) underset((ii)H_(2)O_(2)//OH^(bar(..)))overset((i)BH_(3)//THF)rarrZ . Z is :

Borane is an electron deficient compound. It has only six valence eletons, so the boron atom lacks an octet. Acquiring an octet is the driving force for the unusual bonding structure found in boron compounds. As an electron deficient compound, BH_(3) is a strong electrophile, capable of adding to a double bond. This hydroboration of double bond is though to oC Cur in one step, with the boron atom adding to the less highly substituted end of the double bond. In transition state, the boron atom withdraws electrons from the pi bond and the carbon at theother end of the double bond acquires a partial positive charge. This positive charge is more stable on the more highly subsituted carbon atom. The second step is the oxidation of boron atom, removing it from carbon and replacing it with hydroxyl group by using H_(2)O_(2)//OH^(bar(..)) . The simultaneous addition of boron and hydrogen to the double bond leads to a syn addition. Oxidation of the trialkyl borane replaces boron with a hydroxyl group in the same stereochemical position. Thus, hydroboration of alkenen is an example of steropecific reaction, in which different steroisomers of starting compounds react to give different steroisomers of the product. Find the product of following reaction

AAKASH INSTITUTE-HYDROCARBONS-Assignment(Section - D) (Assertion -Reason Type Question)
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  2. A : In alkene, hydroboration oxidation process is an example of pericy...

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  4. A : On dehydration with concentrated H(2)SO(4) neopentyl alcohul gives...

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  5. A : Generally, n-hexane and onwards can be sulphonated but isobutane a...

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  6. A : When 2-fluoro butane is reacted with alcoholic KOH then butene-1 i...

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  7. A: When butyne-2 is reacted with Na/liq. NH(3) then trans-butene-2 is ...

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  8. A : has 12 pieelectrons i.e. 4n, pie electrons. R : It is an antiaro...

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  9. A : Propene reacts with HBr in presence of H(2)O(2) gives 2-bromopropa...

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  10. A : Boiling point of n-pentane is more than neopentane but the melting...

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  11. A : Alkynes is more reactive than alkene towards electrophilic additio...

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  12. A : But-1-yne has acidic hydrogen but but-2-yne does not R : In but-...

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  13. A : CH(3)-CH(2)-underset(F)underset(|)CH-CH(3) on reaction with KNH(2)...

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  14. A : Methane cannot be prepared by kolbe electrolytic reaction. R : In...

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  15. A : Benzene on reaction with V(2)O(5) gives maleic anhydride at high t...

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  16. A : The rate of sulphonation of benzene and deutrobenzene is different...

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  17. A : Friedel-crafts alkylation of benzene occurs in the presence of Lew...

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  18. A : The reaction between benzene and (CH(3))(3)C.COCl in the presence ...

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  19. A : Addition of Br(2) in trans-but-2-ene in the presence of CCI(4) giv...

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  20. A : Cyclohexane is more stable than cyclopentane. R : According to B...

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