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A : Alkynes is more reactive than alkene...

A : Alkynes is more reactive than alkene towards electrophilic addition reaction.
R : Alkynes form stable carbocation than alkene.

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion, then mark (1).

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark (2)

C

if Assertion is true statement but Reason is false, then mark (3)

D

If both Assertion and Reason are false statements, then mark (4)

Text Solution

AI Generated Solution

The correct Answer is:
To solve the assertion-reason question regarding the reactivity of alkynes and alkenes towards electrophilic addition reactions, we will analyze both the assertion (A) and the reason (R) step by step. ### Step 1: Analyze the Assertion (A) **Assertion (A):** Alkynes are more reactive than alkenes towards electrophilic addition reactions. - **Explanation:** Alkynes contain a triple bond (C≡C), which consists of one sigma bond and two pi bonds. The presence of multiple pi bonds makes alkynes more reactive in electrophilic addition reactions compared to alkenes, which only have one pi bond (C=C). The greater number of pi bonds in alkynes allows for more sites of reaction with electrophiles, thus making them more reactive. ### Step 2: Analyze the Reason (R) **Reason (R):** Alkynes form more stable carbocations than alkenes. - **Explanation:** When considering the stability of carbocations, we note that the stability of a carbocation increases with the degree of substitution. Alkenes typically form sp² hybridized carbocations, which are less stable than sp³ hybridized carbocations formed from alkynes. However, the assertion that alkynes form more stable carbocations than alkenes is incorrect. In fact, alkenes form more stable carbocations due to the greater electron-donating ability of alkyl groups attached to the positively charged carbon. ### Step 3: Conclusion - **Final Evaluation:** - The assertion (A) is **true**: Alkynes are indeed more reactive than alkenes towards electrophilic addition reactions. - The reason (R) is **false**: Alkynes do not form more stable carbocations than alkenes; in fact, alkenes form more stable carbocations. ### Answer: Both the assertion (A) is true, but the reason (R) is false. Therefore, the correct conclusion is that the assertion is true, but the reason is not a correct explanation of the assertion. ---
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AAKASH INSTITUTE-HYDROCARBONS-Assignment(Section - D) (Assertion -Reason Type Question)
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  2. A : When 2-fluoro butane is reacted with alcoholic KOH then butene-1 i...

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  3. A: When butyne-2 is reacted with Na/liq. NH(3) then trans-butene-2 is ...

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  4. A : has 12 pieelectrons i.e. 4n, pie electrons. R : It is an antiaro...

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  5. A : Propene reacts with HBr in presence of H(2)O(2) gives 2-bromopropa...

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  6. A : Boiling point of n-pentane is more than neopentane but the melting...

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  7. A : Alkynes is more reactive than alkene towards electrophilic additio...

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  8. A : But-1-yne has acidic hydrogen but but-2-yne does not R : In but-...

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  9. A : CH(3)-CH(2)-underset(F)underset(|)CH-CH(3) on reaction with KNH(2)...

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  10. A : Methane cannot be prepared by kolbe electrolytic reaction. R : In...

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  11. A : Benzene on reaction with V(2)O(5) gives maleic anhydride at high t...

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  12. A : The rate of sulphonation of benzene and deutrobenzene is different...

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  13. A : Friedel-crafts alkylation of benzene occurs in the presence of Lew...

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  14. A : The reaction between benzene and (CH(3))(3)C.COCl in the presence ...

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  15. A : Addition of Br(2) in trans-but-2-ene in the presence of CCI(4) giv...

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  16. A : Cyclohexane is more stable than cyclopentane. R : According to B...

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  17. A : Addition of HBr in buta-1, 3-diene gives 3 bromo-but-1-ene as majo...

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  18. A : Gauch conformer of ethylene glycol is most stable R : It is due ...

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  19. A : But-2-ene is more stable than propene. R : Heat of hydrogenation ...

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  20. A : Grignard reagent on reaction with alcohol form alkane. R : Alcoh...

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