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A : CH(3)-CH(2)-underset(F)underset(|)CH...

A : `CH_(3)-CH_(2)-underset(F)underset(|)CH-CH_(3)` on reaction with `KNH_(2)` gives but-1-ene as major product.
R : It follows `E_(1)CB` mechanism.

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion, then mark (1).

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark (2)

C

if Assertion is true statement but Reason is false, then mark (3)

D

If both Assertion and Reason are false statements, then mark (4)

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the reaction of 2-fluorobutane with KNH2 and the mechanism involved, we can break it down into the following steps: ### Step-by-Step Solution: 1. **Identify the Reactant**: - The compound given is 2-fluorobutane, which has the structure: \[ CH_3-CH_2-CH(F)-CH_3 \] - Here, the fluorine (F) is attached to the second carbon of the butane chain. 2. **Understand the Reagent**: - KNH2 (potassium amide) is a strong base. It dissociates in solution to give K⁺ and NH2⁻ (amide ion), where NH2⁻ is the active species for the reaction. 3. **Mechanism Overview**: - The E1CB (Elimination Unimolecular Conjugate Base) mechanism is favored here due to the presence of a poor leaving group (fluorine) and a strong base (NH2⁻). 4. **First Step - Deprotonation**: - The strong base (NH2⁻) will first deprotonate a hydrogen atom adjacent to the carbon bearing the fluorine (the β-hydrogen). This leads to the formation of a carbanion. - The structure after deprotonation will be: \[ CH_3-CH_2-CH^(-)-CH_3 \] - Here, the negative charge is on the β-carbon. 5. **Stability of the Carbanion**: - The stability of the carbanion is crucial. The carbanion formed can be stabilized by the adjacent alkyl groups. In this case, the carbanion formed at the β-carbon is more stable due to the inductive effect of the adjacent alkyl groups. 6. **Second Step - Leaving Group Departure**: - The next step involves the departure of the leaving group (F). This is the rate-determining step of the E1CB mechanism. - The structure changes to: \[ CH_3-CH_2-CH=CH_2 \] - This results in the formation of but-1-ene. 7. **Final Product**: - The major product of the reaction is but-1-ene. ### Conclusion: - The assertion that 2-fluorobutane reacts with KNH2 to give but-1-ene as the major product is correct. - The reason that it follows the E1CB mechanism is also correct, as it involves a poor leaving group and a strong base.
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