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Neutral FeCl(3) gives purple colour w...

Neutral ` FeCl_(3)` gives purple colour with

A

Only phenol

B

p-cresol

C

2,4,6-tribromophenol

D

All of these

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The correct Answer is:
To solve the question regarding which compound gives a purple color with neutral FeCl₃, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding FeCl₃**: - FeCl₃ (iron(III) chloride) dissociates in solution to form Fe³⁺ ions and Cl⁻ ions. The Fe³⁺ ions are responsible for forming complexes with certain organic compounds. **Hint**: Remember that FeCl₃ breaks down into Fe³⁺ and Cl⁻ ions when dissolved in water. 2. **Identifying the Phenoxide Ion**: - Phenols can lose a hydrogen ion (H⁺) to form a phenoxide ion (C₆H₅O⁻). This ion can then react with Fe³⁺ to form a colored complex. **Hint**: Look for compounds that can release a phenoxide ion when they react with a base or in solution. 3. **Reaction of Phenol with FeCl₃**: - When phenol (C₆H₅OH) reacts with FeCl₃, it forms a phenoxide ion (C₆H₅O⁻) and a purple complex with Fe³⁺: \[ \text{C₆H₅OH} \rightarrow \text{C₆H₅O}⁻ + \text{H}⁺ \] \[ \text{Fe}^{3+} + \text{C₆H₅O}⁻ \rightarrow \text{Fe(C₆H₅O)₃} \quad \text{(purple complex)} \] **Hint**: Identify the specific reaction that leads to the formation of the purple complex. 4. **Analyzing the Given Compounds**: - Check each compound to see if it can produce a phenoxide ion. For example: - **Phenol (C₆H₅OH)**: Can form phenoxide ion. - **2,4,6-Tribromophenol**: Still retains the phenolic structure and can also form a phenoxide ion. - **Any other compound**: Must be evaluated similarly. **Hint**: Look for the presence of the hydroxyl (-OH) group in the compounds, as it indicates the potential to form a phenoxide ion. 5. **Conclusion**: - Since all the compounds mentioned can produce a phenoxide ion, they will all react with FeCl₃ to form the purple complex. **Final Answer**: All of the given compounds will give a purple color with neutral FeCl₃. ### Summary: - The compounds that can form phenoxide ions will react with Fe³⁺ from FeCl₃ to produce a purple complex. Therefore, the answer is that all of the mentioned compounds will give a purple color with neutral FeCl₃.
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