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A : When C(2) H(5) - O- CH(3) is reacte...

A : When `C_(2) H_(5) - O- CH_(3)` is reacted with oen mole of Hl then `C_(2)H_(5)OH& CH_(3) l` is formed .
R : It is `S_(N)1` reaction

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion, then mark (1)

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark (2)

C

If Assertion is true statement but Reason is false , then mark (3)

D

If both Assertion and Reason are false statements , then mark (4)

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the assertion and reasoning provided: ### Assertion (A): When \( C_2H_5 - O - CH_3 \) is reacted with one mole of HI, then \( C_2H_5OH \) and \( CH_3I \) are formed. ### Reason (R): It is an \( S_N1 \) reaction. ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactant is an ether, specifically ethyl methyl ether, represented as \( C_2H_5 - O - CH_3 \). 2. **Reaction with HI**: When this ether reacts with hydroiodic acid (HI), the ether undergoes cleavage. The reaction can be represented as: \[ C_2H_5 - O - CH_3 + HI \rightarrow C_2H_5OH + CH_3I \] Here, the ether is cleaved to form ethanol (\( C_2H_5OH \)) and methyl iodide (\( CH_3I \)). 3. **Mechanism of the Reaction**: - The oxygen atom in the ether has lone pairs and can protonate when it reacts with \( H^+ \) from HI, leading to the formation of a positively charged intermediate. - The bond between the oxygen and the methyl group breaks, leading to the formation of a methyl cation (\( CH_3^+ \)). - However, the methyl cation is unstable, and therefore, the iodide ion (\( I^- \)) attacks the methyl group from the backside, resulting in the formation of methyl iodide (\( CH_3I \)). - The ethyl group remains as ethanol (\( C_2H_5OH \)). 4. **Determine the Type of Reaction**: - The reaction mechanism here is not \( S_N1 \) because \( S_N1 \) involves the formation of a stable carbocation, which is not the case for the methyl group. - Instead, this reaction follows an \( S_N2 \) mechanism, where the nucleophile (iodide ion) attacks the electrophile (methyl group) directly. 5. **Conclusion**: - The assertion is true as the products \( C_2H_5OH \) and \( CH_3I \) are indeed formed. - The reason given is false because the reaction follows an \( S_N2 \) mechanism, not \( S_N1 \). ### Final Answer: - Assertion (A) is true. - Reason (R) is false.
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