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Ketones and 1^(@) amine react to form...

Ketones and `1^(@)` amine react to form

A

Amides

B

Oximes

C

Urea

D

Schiff's bases

Text Solution

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The correct Answer is:
To solve the question "Ketones and `1^(@)` amine react to form", we can follow these steps: ### Step 1: Identify the Reactants We start with a ketone and a primary amine (1° amine). A ketone has the general structure R1C(=O)R2, where R1 and R2 are alkyl or aryl groups. A primary amine has the structure R3NH2, where R3 is an alkyl or aryl group. ### Step 2: Understand the Reaction Mechanism When a ketone reacts with a primary amine, they undergo a condensation reaction. In this reaction, the amine attacks the carbonyl carbon of the ketone. ### Step 3: Formation of the Intermediate The nucleophilic nitrogen from the primary amine attacks the electrophilic carbon of the carbonyl group (C=O) in the ketone. This leads to the formation of a tetrahedral intermediate. ### Step 4: Elimination of Water The tetrahedral intermediate then undergoes dehydration (loss of water) to form an imine. The reaction can be summarized as follows: - Ketone + Primary Amine → Tetrahedral Intermediate → Imine + Water ### Step 5: Identify the Product The product formed is an imine, which has the general structure R1C=N-R3. This compound is also known as a Schiff base. ### Final Answer The reaction of a ketone with a primary amine results in the formation of a Schiff base (an imine).
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