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C2H5CNoverset(HNO(2))toAoverset(PCl(5))t...

`C_2H_5CNoverset(HNO_(2))toAoverset(PCl_(5))toBoverset(NH_(3))toC` end product in the given sequence is

A

`C_2H_5CN`

B

`CH_3NH_2`

C

`C_2H_5NH_2`

D

`CH_3CONH_2`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, we will analyze each reaction in the sequence provided: ### Step 1: Reaction of Ethyl Cyanide with Nitrous Acid **Reaction:** Ethyl cyanide (C₂H₅C≡N) reacts with nitrous acid (HNO₂) at low temperatures (0 to 5 degrees Celsius). **Product:** This reaction leads to the formation of an unstable diazonium compound (A). The diazonium compound is not stable and will undergo hydrolysis. ### Step 2: Hydrolysis of the Diazonium Compound **Hydrolysis:** The unstable diazonium compound (A) is hydrolyzed in the presence of water. **Product:** The hydrolysis of the diazonium compound yields a carboxylic acid, specifically ethanoic acid (acetate) or ethyl carbamate (C₂H₅COOH). However, in this context, we will focus on the formation of ethyl chloride (C₂H₅Cl) as we proceed to the next step. ### Step 3: Reaction of Ethyl Chloride with PCl₅ **Reaction:** The ethyl chloride (C₂H₅Cl) is then treated with phosphorus pentachloride (PCl₅). **Product:** This reaction will convert the ethyl chloride into a more reactive intermediate, which is typically an alkyl chloride. However, in this case, it is important to note that PCl₅ can also facilitate the conversion of the alcohol or amine derivatives. ### Step 4: Reaction of the Intermediate with Ammonia **Reaction:** The product from the previous step (B) is then reacted with ammonia (NH₃). **Product:** This reaction leads to the formation of ethyl amine (C₂H₅NH₂) as the final product (C). During this reaction, hydrochloric acid (HCl) is released as a by-product. ### Final Product After analyzing all the steps, the end product (C) in the given sequence is ethyl amine (C₂H₅NH₂). ### Summary of Steps: 1. Ethyl cyanide reacts with nitrous acid to form an unstable diazonium compound (A). 2. The diazonium compound undergoes hydrolysis to yield ethyl chloride (B). 3. Ethyl chloride reacts with PCl₅ to form a reactive intermediate. 4. The intermediate reacts with ammonia to produce ethyl amine (C). ### Final Answer: The end product in the given sequence is **ethyl amine (C₂H₅NH₂)**. ---
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