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An amine reacts with CH(3)SO(2)Cl and th...

An amine reacts with `CH_(3)SO_(2)Cl` and the product is soluble in alkali, amine is

A

`1^(@)` amine

B

`2^(@)` amine

C

`3^(@)` amine

D

All of these

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to identify the type of amine that reacts with methyl sulfonyl chloride (CH₃SO₂Cl) and produces a product that is soluble in alkali. We can analyze the reactions of different types of amines with this reagent. ### Step-by-Step Solution: 1. **Understanding the Reaction**: Methyl sulfonyl chloride (CH₃SO₂Cl) is a sulfonyl chloride that can react with amines. The reaction is known as the Hinsberg reaction, which is used to differentiate between primary, secondary, and tertiary amines. 2. **Reactions with Different Amines**: - **Primary Amine**: When a primary amine reacts with CH₃SO₂Cl, it forms a sulfonamide and releases HCl. The resulting sulfonamide has an acidic hydrogen, making it soluble in alkali. - **Secondary Amine**: A secondary amine will also react with CH₃SO₂Cl, but the product formed does not have an acidic hydrogen. Therefore, it is insoluble in alkali. - **Tertiary Amine**: Tertiary amines do not react with sulfonyl chlorides because they lack a hydrogen atom on the nitrogen to form HCl. Thus, no product is formed. 3. **Conclusion**: Since the product formed from the reaction must be soluble in alkali, the only type of amine that fits this criterion is a primary amine. Therefore, the amine in question is a primary amine. ### Final Answer: The amine is a primary amine. ---
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