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A compound with molecular formula C(6)H(...

A compound with molecular formula `C_(6)H_(14)` has two tertiary carbons. Its IUPAC name is

A

n-hexane

B

2-methyl pentane

C

2,3-dimethyl butane

D

2,3-dimethyl pentane

Text Solution

AI Generated Solution

The correct Answer is:
To determine the IUPAC name of a compound with the molecular formula \(C_6H_{14}\) that contains two tertiary carbon atoms, we can follow these steps: ### Step 1: Understand Tertiary Carbons A tertiary carbon is defined as a carbon atom that is bonded to three other carbon atoms. This means we need to identify structures that contain such carbon atoms. ### Step 2: Identify Possible Structures We will consider various structural isomers of \(C_6H_{14}\) and check for the presence of two tertiary carbons. 1. **n-Hexane**: This is a straight-chain alkane with the structure: \[ CH_3-CH_2-CH_2-CH_2-CH_2-CH_3 \] - **Tertiary Carbons**: 0 (none of the carbons are bonded to three other carbons). 2. **2-Methylpentane**: This structure has a five-carbon chain with a methyl group on the second carbon: \[ CH_3-CH(CH_3)-CH_2-CH_2-CH_3 \] - **Tertiary Carbons**: 1 (the second carbon is bonded to three carbons). 3. **3-Methylpentane**: This structure has a five-carbon chain with a methyl group on the third carbon: \[ CH_3-CH_2-CH(CH_3)-CH_2-CH_3 \] - **Tertiary Carbons**: 1 (the third carbon is bonded to three carbons). 4. **2,2-Dimethylbutane**: This structure has a four-carbon chain with two methyl groups on the second carbon: \[ CH_3-C(CH_3)_2-CH_2-CH_3 \] - **Tertiary Carbons**: 1 (the second carbon is bonded to three carbons). 5. **2,3-Dimethylbutane**: This structure has a four-carbon chain with methyl groups on the second and third carbons: \[ CH_3-CH(CH_3)-CH(CH_3)-CH_3 \] - **Tertiary Carbons**: 2 (the second and third carbons are both bonded to three carbons). ### Step 3: Confirm the Molecular Formula Now, we need to ensure that the structure we found has the correct molecular formula \(C_6H_{14}\): - **2,3-Dimethylbutane** has: - Total Carbons: \(4\) (from butane) + \(2\) (from two methyl groups) = \(6\) - Total Hydrogens: \(2 \times 4 + 2 = 14\) ### Step 4: Conclusion The compound with the molecular formula \(C_6H_{14}\) that has two tertiary carbon atoms is **2,3-dimethylbutane**. ### Final Answer The IUPAC name of the compound is **2,3-dimethylbutane**. ---
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Knowledge Check

  • The compound with molecular formula, C_(6)H_(14) has two tertiary carbons. Its IUPAC name is

    A
    n-hexane
    B
    2-methylpentane
    C
    2, 3-dimethylbutane
    D
    2, 3-dimethylpentane
  • Ethane with the molecular formula C_(2)H_(6) has

    A
    6 covalent bonds.
    B
    7 covalent bonds.
    C
    8 covalent bonds.
    D
    9 covalent bonds.
  • Ethane, with the molecular formula C_(2)H_(6) has

    A
    6 covalent bonds
    B
    7 covalent bonds
    C
    8 covalent bonds
    D
    9 covalent bonds
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