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Which amongst the following is the most ...

Which amongst the following is the most stable carbocation :-

A

`CH_(2)overset(oplus)CH_(2)`

B

`overset(oplus)CH_(2)`

C

`CH_(3) - undersetunderset(CH_(2))(|)C^(oplus)`

D

`CH_(3) - undersetunderset(CH_(3))(|)overset(oplus)CH`

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To determine which carbocation is the most stable, we need to analyze the stability of different types of carbocations based on their structure and the effects of substituents. ### Step-by-Step Solution: 1. **Understand Carbocations**: Carbocations are positively charged carbon species that are electron deficient. Their stability is influenced by the number of alkyl groups attached to the positively charged carbon. More alkyl groups typically lead to greater stability due to hyperconjugation and inductive effects. 2. **Identify the Types of Carbocations**: The stability of carbocations can be classified as: - **Primary (1°)**: A carbocation with one alkyl group attached to the positively charged carbon. - **Secondary (2°)**: A carbocation with two alkyl groups attached. - **Tertiary (3°)**: A carbocation with three alkyl groups attached. 3. **Analyze the Given Carbocations**: Let's denote the carbocations as follows: - **1° Carbocation (CH3-CH2+)**: One alkyl group. - **2° Carbocation (CH3-CH+-CH3)**: Two alkyl groups. - **3° Carbocation (CH3-C+-(CH3)2)**: Three alkyl groups. - **Methyl Carbocation (CH3+)**: No alkyl groups. 4. **Evaluate Stability**: - The **methyl carbocation** (CH3+) is the least stable because it has no alkyl groups to stabilize the positive charge. - The **1° carbocation** (CH3-CH2+) is more stable than the methyl carbocation but less stable than the 2° and 3° carbocations. - The **2° carbocation** (CH3-CH+-CH3) is more stable than the 1° carbocation due to the presence of two alkyl groups. - The **3° carbocation** (CH3-C+-(CH3)2) is the most stable due to the presence of three alkyl groups, which provide maximum stabilization through hyperconjugation and inductive effects. 5. **Conclusion**: Based on the analysis, the most stable carbocation among the options is the **3° carbocation**. ### Final Answer: The most stable carbocation is the **3° carbocation**.
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NARAYNA-SOME BASIC PRINCIPLES AND TECHNIQUES-EXERCISE - III (PREVIOUS YEARS EXAMS QUESTIONS)
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  2. The correct increasing order of the reactivity of halides for S(N)' re...

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  3. Arrange the following in correct order of nucleophilicity :- CH(3)-O...

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  4. Which amongst the following is the most stable carbocation :-

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  5. Which one of the following compounds is most acidic :-

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  6. Pyridine is less basic than triethylamine because .

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  7. Which of the following is more basic than aniline? .

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  8. Nucleophilic addition reaction will be most favoured in :

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  9. Which of the following presents the correct order of the acidity in th...

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  10. Arrange the following for reducing power : (a) I^(-) (b) Cl^(-...

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  11. The order of decreasing reactivity towards electrophilic reagent for t...

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  12. Which one of the following is most reactive towards electrophilic atta...

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  13. Among the following four compounds (a) Phenol (b) methyl phenol ...

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  14. Which of the following species is not electrophilic in nature

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  15. Which one of the following is most reactive towards electrophilic reag...

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  16. Which one is a nucleophilic substitution reaction among the following?

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  17. Which of the following compounds is most basic ?

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  18. The correct increasing order of reactivity for following molecules tow...

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  19. The correct decreasing order of pK(b) is :-

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  20. Given The enthalpy of hydrogenation of these compounds will be ...

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