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Assertion (A) : Except Fluorine all othe...

Assertion (A) : Except Fluorine all other Halogense exhibits `+1,+3,+5,+7` oxidation states in combined state
Reason R: Other halogens have d-robitals and can expand there octet and show `+1,+3,+5,+7` oxidation states.

A

A & R are true, R is correct explanation of A

B

A & R are true, R is not correct explanation of A

C

A is true, but R is false

D

A is false, but R is true

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the assertion and reason provided in the question, we will break down the information step by step. ### Step-by-Step Solution: 1. **Understanding the Assertion (A)**: - The assertion states that "Except Fluorine, all other Halogens exhibit +1, +3, +5, +7 oxidation states in the combined state." - Halogens include Fluorine (F), Chlorine (Cl), Bromine (Br), and Iodine (I). - Fluorine, being the most electronegative element, typically exhibits only a -1 oxidation state in compounds and does not show positive oxidation states. 2. **Analyzing the Oxidation States of Other Halogens**: - Chlorine (Cl) can exhibit oxidation states of +1, +3, +5, and +7 in various compounds: - Example: ClF (Cl in +1), ClO3^- (Cl in +5), ClF3 (Cl in +3), ClO4^- (Cl in +7). - Bromine (Br) and Iodine (I) also exhibit similar oxidation states: - Example: BrF (Br in +1), BrO3^- (Br in +5), ICl (I in +1), ICl3 (I in +3), IO4^- (I in +7). 3. **Understanding the Reason (R)**: - The reason states that "Other halogens have d-orbitals and can expand their octet and show +1, +3, +5, +7 oxidation states." - Chlorine, Bromine, and Iodine have available d-orbitals (3d, 4d, and 5d respectively) that allow them to accommodate more than eight electrons, thus enabling them to exhibit higher oxidation states. 4. **Fluorine's Limitation**: - Fluorine (atomic number 9) has no available d-orbitals (it only has 2s and 2p orbitals) and thus cannot expand its octet. This limits its oxidation states to -1 and 0. 5. **Conclusion**: - Both the assertion and reason are correct. The assertion correctly identifies the oxidation states of halogens, and the reason explains why this is the case for all halogens except Fluorine. ### Final Answer: - **Assertion (A)** is true. - **Reason (R)** is true and correctly explains the assertion.

To analyze the assertion and reason provided in the question, we will break down the information step by step. ### Step-by-Step Solution: 1. **Understanding the Assertion (A)**: - The assertion states that "Except Fluorine, all other Halogens exhibit +1, +3, +5, +7 oxidation states in the combined state." - Halogens include Fluorine (F), Chlorine (Cl), Bromine (Br), and Iodine (I). - Fluorine, being the most electronegative element, typically exhibits only a -1 oxidation state in compounds and does not show positive oxidation states. ...
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NARAYNA- ELECTRO CHEMISTRY-SUBJECTIVE QUESTIONS
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  9. Calculate the quantity of electricity that would be required to reduce...

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  20. The standard reduction potential at 25^(@)C of the reaction 2H(2)O+2...

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