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Match the following {:(,"Set-I (Cl-O b...

Match the following
`{:(,"Set-I (Cl-O bond length",,"Set-II"(A)),((A),HClO,(1),1.64),((B),HClO_(2),(2),1.70),((C),HClO_(3),(3),1.45),((D),HClO_(4),(4),1.57):}`
Correct the matching is

A

`{:(,A,B,C,D),((1),1,2,3,4):}`

B

`{:(,A,B,C,D),((2),2,3,4,1):}`

C

`{:(,A,B,C,D),((3),2,1,4,3):}`

D

`{:(,A,B,C,D),((4),2,1,3,4):}`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem of matching the bond lengths of Cl-O in various compounds, we will analyze the structures of the compounds given in Set-I and their respective bond lengths in Set-II. ### Step-by-Step Solution: 1. **Identify the Compounds**: The compounds we need to analyze are: - HClO (Hypochlorous acid) - HClO₂ (Chlorous acid) - HClO₃ (Chloric acid) - HClO₄ (Perchloric acid) 2. **Draw the Structures**: - **HClO**: The structure is HO-Cl=O (single bond between Cl and O, double bond between Cl and O). - **HClO₂**: The structure is HO-Cl(=O)-O (one single bond and one double bond). - **HClO₃**: The structure is HO-Cl(=O)-O(=O) (two double bonds and one single bond). - **HClO₄**: The structure is HO-Cl(=O)-O(=O)-O(=O) (three double bonds and one single bond). 3. **Analyze Bond Lengths**: - The bond length of Cl-O will vary based on the number of double bonds present. - Generally, single bonds are longer than double bonds. The more double bonds present, the shorter the bond length. - Therefore, we can expect the following order of bond lengths based on the structures: - HClO (single bond) will have the longest bond length. - HClO₄ (three double bonds) will have the shortest bond length. - HClO₂ and HClO₃ will fall in between. 4. **Assign Bond Lengths**: - HClO: 1.64 Å (longest) - HClO₂: 1.70 Å - HClO₃: 1.45 Å - HClO₄: 1.57 Å (shortest) 5. **Match the Sets**: - From the analysis, we can match: - HClO (1.64) → (A) - HClO₂ (1.70) → (B) - HClO₃ (1.45) → (C) - HClO₄ (1.57) → (D) 6. **Final Matching**: - Therefore, the correct matching is: - (A) → (1) - (B) → (2) - (C) → (3) - (D) → (4) ### Conclusion: The correct matching is: - HClO (1.64) → (A) - HClO₂ (1.70) → (B) - HClO₃ (1.45) → (C) - HClO₄ (1.57) → (D)

To solve the problem of matching the bond lengths of Cl-O in various compounds, we will analyze the structures of the compounds given in Set-I and their respective bond lengths in Set-II. ### Step-by-Step Solution: 1. **Identify the Compounds**: The compounds we need to analyze are: - HClO (Hypochlorous acid) - HClO₂ (Chlorous acid) - HClO₃ (Chloric acid) ...
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