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Why has phenol smaller dipole moment tha...

Why has phenol smaller dipole moment than methanol ?

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`CH_(3)` group is electron releasing group and therefore, it increases the negative charge on the oxygen atom in `CH_(3)COH`. Therefore, C-O bond in it is more polar and hence methanol has high dipole moment. Phenyl group is electron attracting group and it reduces negative charge on the oxygen in `C_(6)H_(5)OH`. As a result, C-Obond is less polar in phenol and therefore, phenol has small dipole moment.
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MODERN PUBLICATION-ALCOHOLS, PHENOLS AND ETHERS-CONCEPTUAL QUESTIONS 1
  1. Arrange the following in order of decreasing boiling points (i) Pent...

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  2. What is Jones reagent ? Give the product of oxidation of (i) (ii)...

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  3. Why has phenol higher boiling point than toluene ?

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  4. Out of phenol and benzene, which can be more easily nitrated ?

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  5. Why has phenol smaller dipole moment than methanol ?

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  6. Unlike phenols, alcohols are easily protonated.

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  7. How do you account for the fact that unlike phenol, 2,4-dinitrophenol ...

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  8. Why do alcohols have higher boiling points than haloalkanes of the sam...

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  9. While separating a mixture of ortho- and para-nitrophenols steam disti...

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  10. Explain why is ortho-nitrophenol more acidic than ortho-methoxyphenol ...

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  11. Give the equations of reaction for the preparation of phenol form cume...

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  12. Complete the following reactions: CH(3)CH(2)CH(2)OH overset(SOCl(2))...

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  13. A compound (A) with molecular formula C4H10O on oxidation forms compou...

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  14. A compound (A) reacts with thionylchloride to give a compound (B). (B)...

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  15. An alkoxide ion is a stronger base than hydroxide ion. Justify.

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  16. (a) Why does p-dichlorobenzene have a higher m.p than its o-and m-isom...

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  17. Write the IUPAC name of the given compound: HO-CH(2)-underset(CH(3))...

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  18. Write an isomer of C(2)H(6)OH

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  19. Predict the product in the following reaction:

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  20. How will you convert phenol into salicylic acid ?

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