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Unlike phenols, alcohols are easily prot...

Unlike phenols, alcohols are easily protonated.

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In alchols. The electron releasing inductive effect (+ effect) of the alkyl group attched to the carbon having the -OH group increases the electron density on te oxygen atom. Therefore, alcohols are easily protonated.
`R- overset(* *) underset(* *)O-R+H^(+) hArr R-underset("Protonated alcohol") underset(H) underset(|) overset(* *^(+))O-H`
On the other hand in the case of phenol, the oxygen atom acequire are partial positive cahrge due to resonance. Thus, it is not protonated.
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MODERN PUBLICATION-ALCOHOLS, PHENOLS AND ETHERS-CONCEPTUAL QUESTIONS 1
  1. Arrange the following in order of decreasing boiling points (i) Pent...

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  2. What is Jones reagent ? Give the product of oxidation of (i) (ii)...

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  3. Why has phenol higher boiling point than toluene ?

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  4. Out of phenol and benzene, which can be more easily nitrated ?

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  5. Why has phenol smaller dipole moment than methanol ?

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  6. Unlike phenols, alcohols are easily protonated.

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  7. How do you account for the fact that unlike phenol, 2,4-dinitrophenol ...

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  8. Why do alcohols have higher boiling points than haloalkanes of the sam...

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  9. While separating a mixture of ortho- and para-nitrophenols steam disti...

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  10. Explain why is ortho-nitrophenol more acidic than ortho-methoxyphenol ...

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  11. Give the equations of reaction for the preparation of phenol form cume...

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  12. Complete the following reactions: CH(3)CH(2)CH(2)OH overset(SOCl(2))...

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  13. A compound (A) with molecular formula C4H10O on oxidation forms compou...

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  14. A compound (A) reacts with thionylchloride to give a compound (B). (B)...

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  15. An alkoxide ion is a stronger base than hydroxide ion. Justify.

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  16. (a) Why does p-dichlorobenzene have a higher m.p than its o-and m-isom...

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  17. Write the IUPAC name of the given compound: HO-CH(2)-underset(CH(3))...

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  18. Write an isomer of C(2)H(6)OH

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  19. Predict the product in the following reaction:

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  20. How will you convert phenol into salicylic acid ?

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