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Arrange the given compounds in decreasin...

Arrange the given compounds in decreasing order of acidity and give a suitable explanation, Phenol, o-nitrophenol, o-cresol

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Increasing order of acidity:
0-Cresol `lt` Phenol `lt` 0-Nitrophenol

`(-CH_(3))` gives electrons and intensify the charge on phenoxide ion and therefore makes it unstable. Therefore, o cresol is less acidic than phenol. In o-nitrophenol, the electron withdrawing `(-NO_(2))` group withdraws electrons and disperses the-ve charge and stabilizes the phenoxide ion. Therefore, o-nitrophenol is more acidic than phenol.
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MODERN PUBLICATION-ALCOHOLS, PHENOLS AND ETHERS-NCERT (EXAMPLAR PROBLEMS) (Short Answer Type Questions)
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  8. How can propan-2-one be converted into tert-butyl alcohol ?

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  9. Write the structures of the isomers of alcohols with molecular formula...

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  10. Explain why is OH group in phenols more strongly held as compared to O...

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  11. Explain why nucleophilic substitution reactions are not very common in...

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  12. Preparation of alcohols from alkenes involves the electrophilic attack...

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  13. Explain why is O=C=O non polar while R-O-R is polar ?

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  14. Why is the reactivity of all the three classes of alcohols with conc. ...

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  15. Write steps to carry out the conversion of phenol to aspirin.

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  16. Nitration is an example of aromatic electrophilic substitution and its...

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  17. In Kolbe's reactio insteaded of phenol, phenoxide ion is treated with ...

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  18. Dipole moment of phenol is smaller than that of methanol. Why ?

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  19. Ethers can be prepared by Williamson synthesis in which an alkyl halid...

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  20. Why is the C-O-H bond angle in alcohols slightly less than the tetrahe...

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