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In the following reactions, (a) H(3)C...

In the following reactions,
(a) `H_(3)C-overset(CH_(3))overset("| ")(CH)-underset(" "OH )underset(|)(CH)-CH_(3)overset(H^(+)//heat)rarr underset("product")underset("Major")(A) + underset("product")underset("Minor")(B)`
(b) `A overset(HBr,dark)underset("in absence of peroxide")rarr underset("product")underset("Major")(C)+underset("product")underset("Minor")(D)`
The major products (A) and (C) are respectively:

A

`CH_(2)=overset(CH_(3)) overset(|)C-CH_(2)-CH_(3) and underset(Br) underset(|) (CH_(2))- overset(CH_(3)) overset(|)(CH)-CH_(2)-CH_(3)`

B

`CH_(2)-overset(CH_(3)) overset(|)C=CH-CH_(3) and underset(Br) underset(|) overset(CH_(3)) overset(|)C-CH_(2)-CH_(3)`

C

`CH_(2)-overset(CH_(3)) overset(|)C=CH-CH_(3) and CH_(3)-overset(CH_(3)) overset(|)C- underset(Br) underset(|)CH-CH_(3)`

D

`CH_(2)=overset(CH_(3)) overset(|)C-CH_(2)-CH_(3) and CH_(3)- underset(Br) underset(|)overset(CH_(3)) overset(|)C-CH_(2)-CH_(3)`

Text Solution

Verified by Experts

The correct Answer is:
B

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