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Predict the product formed when cycl...

Predict the product formed when cyclohexanecarbaldehyde reacts with following reagents :
(I ) PhMgBr and then ` H_2O^+` (ii ) Tollen's ethanool and acid
(v ) Zinc amalgam and dilute hydrochoric acid

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To predict the products formed when cyclohexanecarbaldehyde reacts with the given reagents, we will analyze each reaction step-by-step. ### Step 1: Reaction with PhMgBr followed by H2O 1. **Identify the Reactants**: Cyclohexanecarbaldehyde (C6H11CHO) is an aldehyde. The Grignard reagent PhMgBr is a strong nucleophile. 2. **Nucleophilic Attack**: The nucleophilic phenyl group (Ph-) from PhMgBr attacks the electrophilic carbon of the carbonyl group (C=O) in cyclohexanecarbaldehyde. This results in the formation of a tetrahedral intermediate. 3. **Formation of Alkoxide**: The tetrahedral intermediate collapses, leading to the formation of an alkoxide ion (C6H11C(OH)(Ph)). 4. **Hydrolysis**: When the alkoxide is treated with water (H2O), it is protonated to form the corresponding alcohol. 5. **Final Product**: The final product after hydrolysis is 1-phenylcyclohexanol (C6H11C(OH)(Ph)). ...
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MODERN PUBLICATION-ALDEHYDES ,KETONES AND CARBOXYLIC ACIDS-NCERT FILE (NCERT TEXTBOOK EXERCISES )
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  2. Name the following compounds according to IUPAC system of nomoen...

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  3. Draw the structures of following compound: i. 3-Methylbutanal ii. ...

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  4. Write the IUPAC names of the ketons and aldehydes wherever poss...

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  5. Draw the structure of following derivatives: i. 2,4-Dinitrophylhydra...

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  6. Predict the product formed when cyclohexanecarbaldehyde reacts wi...

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  7. Which of the following compounds would undergo aldol condensation or t...

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  8. How will you convert ethnal into the following compounds ? i. Butane...

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  9. Write structure formulae and names of four possible aldol condensation...

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  10. An organic compound with the molecular folmula C(9)H(10)O form 2,4-DNP...

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  11. An organic compound (A) (molecular formula C(8)H(16)O(2)) was hydrolys...

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  12. Arrange the following compounds in the increasing order of their prope...

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  13. Give simple chemical test to distinguish between the following pairs o...

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  14. How will you prapare the following compounds from benzene ? You may us...

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  15. How will you bring about the following conversions in not more than tw...

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  16. Describe the following i. Acetylation ii. Cannizzaro reaction i...

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  17. complete each synthesis by giving missing starting material , r...

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  18. Giving plausible explanation for each of the following: i. Cyclohexa...

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  19. An organic compound contains 69.77% carbon, 11.63% hydrogen, and rest ...

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  20. Although phenoxide ion has more number of resonating structures than c...

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