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How will you convert ethnal into the fol...

How will you convert ethnal into the following compounds ?
i. Butane-1,3-idol , ii. But-2-enal
iii. But-2-enoic acid

Text Solution

Verified by Experts

`( i) 2CH_3 CHO underset( "aldol condensation ") overset(OH^(-)) to CH_3 overset(OH) overset(|) CH - underset("Aldol")(CH_2)- underset(O ) overset(||)C-H overset(LiAIH_4) to underset("Butane -1,3-diol") (CH_3 overset(OH) overset(| ) CH-CH_2CH_2OH)`
(ii ) `2CH_3 CHO CHO underset("Aldol condensation") overset(OH^-) to CH_3 overset(OH) overset(|)CH -CH_2CHO underset("Heat")overset(H^+) to CH_3 underset("Butane -2-enal ") (CH_4 CH=CH-CHO)`
`(iii ) 2CH_3 CHO underset("aldol condensation ") overset(OH^(-)) to CH_3 overset(OH) overset(|) CH CH_2 CHO underset("heat")overset(H^(+) .H_2 O) to CH_3 CH= CH-CHO overset( LiAIH_4 , H^+) to {:(CH_3 CH=CHCH_2 OH ),( darr KMO_4 ","H^+),(CH_3 CH =CHCOOH),("but -2- enoic acid "):}`
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MODERN PUBLICATION-ALDEHYDES ,KETONES AND CARBOXYLIC ACIDS-NCERT FILE (NCERT TEXTBOOK EXERCISES )
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  2. Name the following compounds according to IUPAC system of nomoen...

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  3. Draw the structures of following compound: i. 3-Methylbutanal ii. ...

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  4. Write the IUPAC names of the ketons and aldehydes wherever poss...

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  5. Draw the structure of following derivatives: i. 2,4-Dinitrophylhydra...

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  6. Predict the product formed when cyclohexanecarbaldehyde reacts wi...

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  7. Which of the following compounds would undergo aldol condensation or t...

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  8. How will you convert ethnal into the following compounds ? i. Butane...

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  9. Write structure formulae and names of four possible aldol condensation...

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  10. An organic compound with the molecular folmula C(9)H(10)O form 2,4-DNP...

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  11. An organic compound (A) (molecular formula C(8)H(16)O(2)) was hydrolys...

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  12. Arrange the following compounds in the increasing order of their prope...

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  13. Give simple chemical test to distinguish between the following pairs o...

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  14. How will you prapare the following compounds from benzene ? You may us...

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  15. How will you bring about the following conversions in not more than tw...

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  16. Describe the following i. Acetylation ii. Cannizzaro reaction i...

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  17. complete each synthesis by giving missing starting material , r...

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  18. Giving plausible explanation for each of the following: i. Cyclohexa...

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  19. An organic compound contains 69.77% carbon, 11.63% hydrogen, and rest ...

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  20. Although phenoxide ion has more number of resonating structures than c...

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