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Aldehydes are less easily oxidised than ...

Aldehydes are less easily oxidised than ketones.

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To determine whether the statement "Aldehydes are less easily oxidized than ketones" is true or false, we can analyze the oxidation reactions of both aldehydes and ketones step by step. ### Step 1: Understanding Aldehydes and Ketones - **Aldehydes** have the general formula RCHO, where R is a hydrocarbon group. - **Ketones** have the general formula RC(=O)R', where R and R' are hydrocarbon groups. ### Step 2: Oxidation of Aldehydes - When aldehydes are oxidized, they typically convert to **carboxylic acids**. - Common oxidizing agents include concentrated nitric acid (HNO3), potassium permanganate (KMnO4) in acidic conditions, and potassium dichromate (K2Cr2O7). - The oxidation process involves breaking the C-H bond in the aldehyde, which is relatively easier due to the presence of the hydrogen atom bonded to the carbonyl carbon. ### Step 3: Oxidation of Ketones - Ketones can also be oxidized, but the process is different. When oxidized, ketones can break the C-C bond adjacent to the carbonyl group, leading to the formation of smaller carboxylic acids. - According to Popov's rule, the larger alkyl group (R') will remain intact while the smaller alkyl group (R) is oxidized to a carboxylic acid. - The oxidation of ketones is generally more difficult compared to aldehydes because ketones lack a hydrogen atom directly bonded to the carbonyl carbon, making the C-C bond stronger and more stable. ### Step 4: Comparing the Ease of Oxidation - Since aldehydes can be oxidized more easily due to the presence of a hydrogen atom bonded to the carbonyl carbon, they are more susceptible to oxidation than ketones. - In contrast, ketones require breaking a C-C bond, which is a stronger bond and thus requires more energy. ### Conclusion - Therefore, the statement "Aldehydes are less easily oxidized than ketones" is **false**. Aldehydes are more easily oxidized than ketones.
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Explain why aldehydes are more reactios than ketones.

Statement -I: Fehling ' s reagent is a test for all aliphatic aldehydes. Statement-II : Aliphatic aldehydes can be easily oxidised even with mild oxidising agents.

MODERN PUBLICATION-ALDEHYDES ,KETONES AND CARBOXYLIC ACIDS-QUICK MEMORY TEST ( A. SAY TRUE OR FALSE )
  1. Aldehydes and ketones react with electrophiles but not with nucleophil...

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  2. Wolff Kishner reduction of acetophenone gives toluene.

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  3. Acetaldehyde can be prepared by the distillation of calcium acetate.

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  4. Acetaldehyde can be reduced to ethane in the presence of LiAlH4.

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  5. Benzaldehyde cannot undergo Cannizzaro reaction.

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  6. Aldehydes are less easily oxidised than ketones.

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  7. Acetaldehyde cyanohydrin on hydrolysis gives lactic acid.

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  8. Benzaldehyde reduces Fehling solution.

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  9. Benzaldehyde forms addition product with sodium bisulphite but acetoph...

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  10. Ketones give nucleophilic addition reactions more readily than aldehyd...

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  11. Calcium formate on heating gives acetaldehyde.

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  12. The pKa value of formic acid is smaller than that of acetic acid.( Tru...

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  13. The carbon-oxygen bond lengths in formic acid are equal.

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  14. Nitration of benzoic acid gives m-nitrobenzoic acid.

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  15. During the reaction of carboxylic acid with NaHCO2 the carbon of the C...

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  16. When benzoic acid is heated with soda lime, benzene is formed.

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  17. Acetate ion is a stronger acid than methoxide ion.

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  18. Ethanoic acid liberates hydrogen with sodium metal.

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  19. Me3 C CH2 COOH is more acidic than Me3 SiCH2 COOH.

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  20. Formic acid gives silver mirror test with Tollen's reagent.

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