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Acetaldehyde cyanohydrin on hydrolysis g...

Acetaldehyde cyanohydrin on hydrolysis gives lactic acid.

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To determine whether the statement "Acetaldehyde cyanohydrin on hydrolysis gives lactic acid" is true or false, we will analyze the reaction step by step. ### Step-by-Step Solution: 1. **Identify Acetaldehyde Cyanohydrin Structure**: - The structure of acetaldehyde cyanohydrin is CH3-CHOH-CN. This compound consists of an acetaldehyde group (CH3-CHO) and a cyanohydrin group (C-N). 2. **Understanding Hydrolysis**: - Hydrolysis involves the reaction of a compound with water (H2O) and is often catalyzed by an acid (H+). In this case, we will consider the hydrolysis of the cyanohydrin. 3. **Mechanism of Hydrolysis**: - The hydrolysis of acetaldehyde cyanohydrin can be initiated by the protonation of the cyanide nitrogen, which makes it more susceptible to nucleophilic attack. - The nitrogen atom in the cyanohydrin has a lone pair of electrons and can attack a proton (H+) from the acid, leading to a positively charged nitrogen. 4. **Nucleophilic Attack by Water**: - Water (H2O) acts as a nucleophile and attacks the carbon atom that is bonded to the cyanide group (C≡N). This results in the formation of a tetrahedral intermediate. 5. **Formation of Hydroxylamine**: - After the nucleophilic attack, the intermediate rearranges, leading to the formation of a hydroxylamine derivative. 6. **Tautomerization**: - The intermediate can undergo tautomerization, where the double bond shifts and results in the formation of a carbonyl group (C=O) and an amine group (NH2). 7. **Final Hydrolysis Step**: - Another water molecule can attack the carbonyl carbon, leading to the formation of a diol (two hydroxyl groups) and eventually resulting in the formation of lactic acid (CH3-CHOH-COOH). 8. **Conclusion**: - The final product of the hydrolysis of acetaldehyde cyanohydrin is indeed lactic acid, confirming that the statement is true. ### Final Answer: The statement "Acetaldehyde cyanohydrin on hydrolysis gives lactic acid" is **True**. ---
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Compound 'A' undergoes formation of cyanohydrin which on hydrolysis gives lactic acid [CH_(3)CH(OH)COOH] Therefore, compound 'A' is :

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The cyanohydrin of a carbonyl compound on hydyrolysis gives lactic acid. The carbonyl compound is

MODERN PUBLICATION-ALDEHYDES ,KETONES AND CARBOXYLIC ACIDS-QUICK MEMORY TEST ( A. SAY TRUE OR FALSE )
  1. Aldehydes and ketones react with electrophiles but not with nucleophil...

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  2. Wolff Kishner reduction of acetophenone gives toluene.

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  3. Acetaldehyde can be prepared by the distillation of calcium acetate.

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  4. Acetaldehyde can be reduced to ethane in the presence of LiAlH4.

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  5. Benzaldehyde cannot undergo Cannizzaro reaction.

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  6. Aldehydes are less easily oxidised than ketones.

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  7. Acetaldehyde cyanohydrin on hydrolysis gives lactic acid.

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  8. Benzaldehyde reduces Fehling solution.

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  9. Benzaldehyde forms addition product with sodium bisulphite but acetoph...

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  10. Ketones give nucleophilic addition reactions more readily than aldehyd...

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  11. Calcium formate on heating gives acetaldehyde.

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  12. The pKa value of formic acid is smaller than that of acetic acid.( Tru...

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  13. The carbon-oxygen bond lengths in formic acid are equal.

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  14. Nitration of benzoic acid gives m-nitrobenzoic acid.

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  15. During the reaction of carboxylic acid with NaHCO2 the carbon of the C...

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  16. When benzoic acid is heated with soda lime, benzene is formed.

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  17. Acetate ion is a stronger acid than methoxide ion.

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  18. Ethanoic acid liberates hydrogen with sodium metal.

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  19. Me3 C CH2 COOH is more acidic than Me3 SiCH2 COOH.

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  20. Formic acid gives silver mirror test with Tollen's reagent.

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