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The carbon-oxygen bond lengths in formic...

The carbon-oxygen bond lengths in formic acid are equal.

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To determine whether the statement "The carbon-oxygen bond lengths in formic acid are equal" is true or false, we need to analyze the structure of formic acid and the concept of resonance. ### Step-by-Step Solution: 1. **Identify the Structure of Formic Acid**: Formic acid (HCOOH) consists of a carbon atom bonded to one hydroxyl group (-OH) and one carbonyl group (C=O). The structural formula can be represented as: \[ H - C(=O) - OH \] 2. **Understanding Bond Types**: In formic acid, there are two types of carbon-oxygen bonds: - One is a double bond (C=O) with a carbonyl oxygen. - The other is a single bond (C-O) with a hydroxyl oxygen. 3. **Resonance Structures**: Formic acid exhibits resonance, which means that the electrons can be delocalized. The resonance structures can be drawn as follows: - One structure has a double bond between carbon and one oxygen and a single bond with the other oxygen. - The other resonance structure shows the double bond shifting, resulting in a negative charge on one oxygen and a positive charge on the other. 4. **Analyzing Bond Lengths**: - The C=O bond (carbonyl) is typically shorter than the C-O bond (hydroxyl) due to the presence of a double bond, which involves more electron density and stronger attraction between the carbon and oxygen. - In the resonance structures, the C=O bond is more stable than the C-O bond, which further supports that the bond lengths will differ. 5. **Conclusion**: Since the C=O bond is shorter than the C-O bond, the statement "The carbon-oxygen bond lengths in formic acid are equal" is **false**. ### Final Answer: The statement is **false**; the carbon-oxygen bond lengths in formic acid are not equal. ---
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MODERN PUBLICATION-ALDEHYDES ,KETONES AND CARBOXYLIC ACIDS-QUICK MEMORY TEST ( A. SAY TRUE OR FALSE )
  1. Aldehydes and ketones react with electrophiles but not with nucleophil...

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  2. Wolff Kishner reduction of acetophenone gives toluene.

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  3. Acetaldehyde can be prepared by the distillation of calcium acetate.

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  4. Acetaldehyde can be reduced to ethane in the presence of LiAlH4.

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  5. Benzaldehyde cannot undergo Cannizzaro reaction.

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  6. Aldehydes are less easily oxidised than ketones.

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  7. Acetaldehyde cyanohydrin on hydrolysis gives lactic acid.

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  8. Benzaldehyde reduces Fehling solution.

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  9. Benzaldehyde forms addition product with sodium bisulphite but acetoph...

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  10. Ketones give nucleophilic addition reactions more readily than aldehyd...

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  11. Calcium formate on heating gives acetaldehyde.

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  12. The pKa value of formic acid is smaller than that of acetic acid.( Tru...

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  13. The carbon-oxygen bond lengths in formic acid are equal.

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  14. Nitration of benzoic acid gives m-nitrobenzoic acid.

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  15. During the reaction of carboxylic acid with NaHCO2 the carbon of the C...

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  16. When benzoic acid is heated with soda lime, benzene is formed.

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  17. Acetate ion is a stronger acid than methoxide ion.

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  18. Ethanoic acid liberates hydrogen with sodium metal.

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  19. Me3 C CH2 COOH is more acidic than Me3 SiCH2 COOH.

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  20. Formic acid gives silver mirror test with Tollen's reagent.

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