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Me3 C CH2 COOH is more acidic than Me3 ...

`Me_3 C CH_2 COOH `is more acidic than `Me_3 SiCH_2 COOH.`

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To determine whether `Me_3CCH_2COOH` is more acidic than `Me_3SiCH_2COOH`, we need to analyze the acidity of both compounds by considering the stability of the anions formed when they lose a proton (H⁺). ### Step-by-Step Solution: 1. **Identify the Structures**: - `Me_3CCH_2COOH` has a tert-butyl group (`Me_3C` or `C(CH₃)₃`) attached to a carboxylic acid (`COOH`). - `Me_3SiCH_2COOH` has a tert-butyl group attached to a silicon atom instead of carbon, followed by a carboxylic acid. 2. **Understanding Acidity**: - Acidity is determined by the ability of a compound to donate a proton (H⁺). When the proton is lost, an anion is formed. - The stability of this anion is crucial; the more stable the anion, the stronger the acid. 3. **Formation of Anions**: - For `Me_3CCH_2COOH`, when it loses H⁺, it forms `Me_3CCH_2COO⁻`. - For `Me_3SiCH_2COOH`, when it loses H⁺, it forms `Me_3SiCH_2COO⁻`. 4. **Analyzing Anion Stability**: - The stability of the anion is influenced by the electronegativity of the atom bonded to the carboxylate group (the COO⁻ part). - Carbon (C) is more electronegative than silicon (Si). This means that in `Me_3CCH_2COO⁻`, the carbon can better stabilize the negative charge on the oxygen due to its higher electronegativity. 5. **Comparing Electronegativity**: - As we move down the group in the periodic table, electronegativity decreases. Therefore, silicon has a lower electronegativity than carbon. - This lower electronegativity means that the anion formed from `Me_3SiCH_2COOH` is less stable than the anion formed from `Me_3CCH_2COOH`. 6. **Conclusion**: - Since the anion from `Me_3CCH_2COOH` is more stable than that from `Me_3SiCH_2COOH`, it follows that `Me_3CCH_2COOH` is indeed more acidic than `Me_3SiCH_2COOH`. ### Final Answer: The statement is **true**: `Me_3CCH_2COOH` is more acidic than `Me_3SiCH_2COOH`.
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(CH_(3))_(3)C CH_(2)COOH is more acidic than (CH_(3))_(3)SiCH_(2)COOH because

Why is CH_(2)=CH-COOH a stronger acid than CH_(3)CH_(2)COOH ?

Explain the following : (a) In gaseous phase, the acidic characters of the following are : (i) CH_3 CH_2 COOH (I) gt CH_3 COOH (II) (ii) ClCH_2COOH (III) gt FCH_2 COOH (IV) (iii) Me_3 C-OH (V) gt MeCH_2 CH_2 CH_2 OH (VI) . (b) Account for the following differences in the acidic characters of the following : (i) (I) Me_3 C-CH_2 -COOH gt (II) Me_3 SICH_2 COOH (ii) (III) H_2 C = CHCH_2 COOH gt (IV) CH_3 CH_2 COOH (iii) (V) HC -= C - CH_2COOH (pK_a 3.22) gt (VI) H_2 C = CH CH_2 COOH (pK_a = 4.35) (iv) CH_(3)-underset(O)underset(||)(C)-CH_(2)-COOH gt (v) (IX) N -= C - CH_2 COOH gt (X) CH_3 COCH_2 -COOH (vi) (XI) PhCh_2 COOH gt (XII) CH_2 = CHCH_2 COOH .

Assertion (A ) : pH value of 0.1 M CH_(3)COOH is more than one. Reason (R ) : CH_(3)COOH is weakly ionised.

Assertion : Acetic acid is weaker acid than CH_3 CH_2 COOH. Reason : due to +I effect of methyl group.

Write the IUPAC names of the following : (i) CH_3 CH= CHCOOH " "(ii ) CH_3CH_2 CH_2 COOH " " (iii ) C_6 H_5 CH_2 COOH " "(iv ) (CH_3 )_3 C COOH (v ) CH_3 CH_2 COCH_2 COOH (vi ) (CH_3)_3 C CH_2 COOH " "(vii ) CH_3 - underset(OH) underset(|)CH-CH_2 COOH

Me_3 overset (Ӫ) C is more stable than overset (Ӫ) C H_3 . The + I effect of the three Me groups in Me_3 overset (Ӫ) C tends to make it more stable than overset (Ӫ) C H_3 .

MODERN PUBLICATION-ALDEHYDES ,KETONES AND CARBOXYLIC ACIDS-QUICK MEMORY TEST ( A. SAY TRUE OR FALSE )
  1. Aldehydes and ketones react with electrophiles but not with nucleophil...

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  2. Wolff Kishner reduction of acetophenone gives toluene.

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  3. Acetaldehyde can be prepared by the distillation of calcium acetate.

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  4. Acetaldehyde can be reduced to ethane in the presence of LiAlH4.

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  5. Benzaldehyde cannot undergo Cannizzaro reaction.

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  6. Aldehydes are less easily oxidised than ketones.

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  7. Acetaldehyde cyanohydrin on hydrolysis gives lactic acid.

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  8. Benzaldehyde reduces Fehling solution.

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  9. Benzaldehyde forms addition product with sodium bisulphite but acetoph...

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  10. Ketones give nucleophilic addition reactions more readily than aldehyd...

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  11. Calcium formate on heating gives acetaldehyde.

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  12. The pKa value of formic acid is smaller than that of acetic acid.( Tru...

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  13. The carbon-oxygen bond lengths in formic acid are equal.

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  14. Nitration of benzoic acid gives m-nitrobenzoic acid.

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  15. During the reaction of carboxylic acid with NaHCO2 the carbon of the C...

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  16. When benzoic acid is heated with soda lime, benzene is formed.

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  17. Acetate ion is a stronger acid than methoxide ion.

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  18. Ethanoic acid liberates hydrogen with sodium metal.

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  19. Me3 C CH2 COOH is more acidic than Me3 SiCH2 COOH.

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  20. Formic acid gives silver mirror test with Tollen's reagent.

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