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CH(3)COCl+H(2)underset("Quinoline")overs...

`CH_(3)COCl+H_(2)underset("Quinoline")overset(Pd//BaSO_(4))rarr`

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`CH_3 COCI +H_2 underset("Quioline ,S" ) overset(Pd -Ba SO_4) to underset("Ethanal")(CH_3CHO +HCI `
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Complete the reactions : (i) CH_(3)-C-=CH+H_(2) underset("quinoline")overset(Pd, BaSO_(4))to (ii) CaC_(2)+H_(2)O (iii) CH_(3)CH= CHCH_(3) underset(Zn, H_(2)O)overset(O_(3))to (iv) HC -=CH overset("Alk" KmnO_(4))to (v) CH_(3)C -=CH overset("hot." KMNO_(4))to

CH-=CHunderset("quinoline")overset(H_(2)//Pd-BaSO_(4))toAoverset(Cl_(2)//H_(2)O)toB , 'B' is

HC-=Chunderset("Quinoline")overset(H_(2)//Pd-BaSO_(4))toAunderset(AlCl_(3))overset(HCl)toBunderset("Dry ether")overset(Na)toC . 'C' is

The reaction - CH_(3)COCl + H_(2) underset(Pd//BaSO_(4))overset("Xylene")(rarr) CH_(3)CHO + HCl is

C_(6)H_(5) "COCl" underset(H_(2))overset(Pd-BaSO_(4))(rarr) Intermediate overset(" Oxidation ")(rarr) Intermediate underset("Dry distillation")overset("Ca-Salt")(rarr) A Compound (A) in above reaction sequence is –

Complete the following reactions : (i) "Isopropyl bromide" to underset("Heat")overset("alc. KOH")to A underset("Peroxide")overset(HBr)to B (ii) "n-Propyl alcohol" underset(443K)overset(Conc. H_(2)O)to A underset("Heat")overset(O_(2)Ag)to B (c) "1, 1, 2, 2-tetrachloroethane" to underset("Heat")overset("Zn, alcohol") to A underset(675K)overset("Iron tube")to B (iv) "Acetylene" to overset(NaNH_(2))to A overset(CH_(3)CH_(2)Br)to B (v) "Propyne" to underset("Quinoline")overset(H_(2), Pd, BaSO_(4))to A underset((ii) Zn, H_(2)O)overset((i)O_(3))to B

(a) Write the products of the following reactions : (i) CH_(3)-underset(O)underset(||)C-CH_(3)overset(Zn-Hg)underset(conc.HCl)rarr? (ii) CH_(3)-underset(O)underset(||)C-Cl+H_(2)overset(Pd-BaSO_(4))rarr? (b) Which acid of each pair shown here would you expect to be stronger? (i) F-CH_(2)-COOH or Cl-CH_(2)-COOH (ii)

(CH_(3))_(2)+HCNrarr[A]overset(H_(3)O^(+))rarr[B]underset("Heat")overset(H_(2)SO_(4))rarr[C]

MODERN PUBLICATION-ALDEHYDES ,KETONES AND CARBOXYLIC ACIDS-REVISION EXERCISES (OBJECTIVE QUESTIONS - VERY SHORT ANSWER QUESTIONS )
  1. Arrange the following compound in an increasing order of their reactiv...

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  2. Arrange the following in the increasing order of their reactivity in n...

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  3. Arrange the following in the increasing order of boiling point: C2 ...

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  4. Describe a test to distinguish between phenol and benzoic acid.

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  5. Arrange the following in the order of increasing acidic strength...

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  6. Arrange the following in the decreasing order of dipole moment: CH3 ...

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  7. In the series of reactions CH3 COOH underset(P2O5)overset(NH3)to A A...

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  8. Write the IUPAC name of CH3 underset(Cl) underset(| ) CH CH2 CHO.

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  9. What is the reagent 'A' used in the following equation? R-COOH over...

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  10. Complete the following reaction : C6H5 COCH3 underset((ii ) KOH " ...

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  11. CH(3)COCl+H(2)underset("Quinoline")overset(Pd//BaSO(4))rarr

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  12. Arrange the following in the increasing order of pKa values: CH3 ...

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  13. Write the IUPAC name of CH3 COCH2 COCH3

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  14. Give the structure of 3-Oxopentanal.

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  15. Write the structural formula of 1-phenylpentan-2-one.

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  16. Write the IUPAC name of CH3 underset(CH2) underset(|) CH-CO-underset(C...

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  17. Write the IUPAC name of the following CH3- CH2-CH= CH- overset(O...

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  18. Write the structure of p-Methylbenzaldehyde molecule.

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  19. Write the structure of 4 chloropentan 2 one

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  20. Write the structure of 2 hydroxybenzoic acid.

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