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Butanal undergoes aldol condensation ...

Butanal undergoes aldol condensation to give

A

`CH_3CH_2 CH_2 underset(OH) underset(|)CHCH_2 CH_2 CH_2CHO`

B

`CH_3 CH_2CH_2 underset(OH) underset(|)CH underset(OH) underset(|) CH CH_2 CHO`

C

`CH_3 CH_2 CH_2 underset(OH) underset(| ) CH underset(CH_2-CH_3) underset(| ) CHCHO`

D

`CH_3CH_2CH_2 underset(OH) underset(| )CH underset(OH ) underset(| ) CH CH_2 CH_2 CH_3`

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The correct Answer is:
To determine the product of the aldol condensation of butanal, we will follow these steps: ### Step 1: Identify the structure of butanal Butanal is an aldehyde with the molecular formula C4H8O. Its structure is: ``` CH3-CH2-CH2-CHO ``` ### Step 2: Understand the aldol condensation process Aldol condensation involves two molecules of an aldehyde or ketone reacting in the presence of a base. The base abstracts an alpha hydrogen from one molecule, forming an enolate ion, which then attacks the carbonyl carbon of another molecule. ### Step 3: Identify the alpha hydrogen In butanal, the alpha carbon (the carbon adjacent to the carbonyl group) has hydrogens that can be abstracted. The alpha hydrogens in butanal are on the second carbon (C2) of the chain. ### Step 4: Form the enolate ion When a base (like NaOH or KOH) is added, it abstracts one of the alpha hydrogens from butanal, forming the enolate ion: ``` CH3-CH2-CH2-C(-)O ``` This enolate ion is now a nucleophile. ### Step 5: Nucleophilic attack The enolate ion attacks the carbonyl carbon of another butanal molecule: ``` CH3-CH2-CH2-C(=O)-H ``` This results in a beta-hydroxy aldehyde. ### Step 6: Form the aldol product The product of this reaction is 3-hydroxybutanal: ``` CH3-CH2-CH(OH)-CH2-CHO ``` ### Step 7: Dehydration to form the final product The beta-hydroxy aldehyde can undergo dehydration (loss of water) to form an α,β-unsaturated aldehyde. The dehydration results in the formation of crotonaldehyde (but-2-enal): ``` CH3-CH=CH-CHO ``` ### Final Product Thus, the final product of the aldol condensation of butanal is crotonaldehyde (but-2-enal). ---

To determine the product of the aldol condensation of butanal, we will follow these steps: ### Step 1: Identify the structure of butanal Butanal is an aldehyde with the molecular formula C4H8O. Its structure is: ``` CH3-CH2-CH2-CHO ``` ...
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MODERN PUBLICATION-ALDEHYDES ,KETONES AND CARBOXYLIC ACIDS-COMPETITION FILE ( OBJECTIVE TYPE QUESTIONS - MULTIPLE CHOICE QUESTIONS (MCQ) ( A. MULTIPLE CHOICE QUESTIONS )
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  2. Which of the following reagents cannot be used to distinguish between ...

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  3. Butanal undergoes aldol condensation to give

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  4. m-Chlorobenzaldehyde on reaction with conc. KOH at room temperature gi...

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  5. Treatment of propionaldehyde with dilute NaOH solution gives

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  6. Benzyl alcohol can be prepared from benzaldehyde by

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  7. The aldol condensationof acetaldehyde results in the formation of :

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  8. An organic compound of molecular formula C(3)H(5)O did not give a silv...

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  9. In the Cannizzaro reaction , which is the slowest step ? 2PhCHOovers...

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  10. Identify the final product (Z) in the following sequence of re...

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  11. in the reaction D is

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  12. In the cannizzaro's reaction the intermediate that will be the best hy...

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  13. An acid chloride on reaction with H2//Pd -BaSO4 gives (CH3 )2 ...

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  14. Which of the following will be most readily dehydrated in acidic condi...

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  15. Acetic acid is reduced with LiAIH4 to give

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  16. Benzoic acid in treament with HNO3 in the presence of H2 SO4 giv...

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  17. In the reaction : CH3 COOH overset(Ca(OH)2) to A overset("Heat...

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  18. The reaction RCH(2)CH(2)COOHunderset(Br(2))overset("RedP")to R-CH(...

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  19. Which of the following is Weakest acid ?

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  20. in the reaction CH3 CH2 COOH overset(P,CI2) to X overset(KCN ) ...

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