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Cellulose upon acetylation with excess a...

Cellulose upon acetylation with excess acetic anhydride/`H_(2)SO_(4)` (catalytic) gives cellulose triacetate whose structure is

A

B

C

D

Text Solution

Verified by Experts

The correct Answer is:
A

Cellulose has `beta-` glycosidic linkages between `C_(1)` of one glucose unit and `C_(4)` of the other. It has three free OH groups at 2, 3, 6 positions and hence Oac group apears at `C_(2), C_(3) and C_(6)` positions.
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Knowledge Check

  • Cellulose upon acetylation with excess anhydride//H_(2)SO_(4) (catalytic) gives cellulose triacetate whose structure is:

    A
    B
    C
    D
  • Cellobiose upon acetylation with excess acetic anhydride / H_(2)SO_4 (catalytic) gives triacetate whose structure is_______.

    A
    B
    C
    D
  • On acetylation with acetic anhydride, glucose gives

    A
    hexaacetate
    B
    pentaacetate
    C
    tetraacetate
    D
    triacetate