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Corrosion of iron is essentially an elec...

Corrosion of iron is essentially an electrochemical phenomenon where the cell reactions are

A

Fe is oxidised to `Fe^(2+)` and dissolved oxygen in water is reduced to `overset(Theta)(OH)`

B

Fe is oxidised to `Fe^(3+)` and `H_(2)O` is reduced to`O_(2)^(2-)`

C

Fe is oxidised to `Fe^(2+)` and `H_(2)O` is reduced to`O_(2)^(-)`

D

Fe is oxidised to `Fe^(2+)` and `H_(2)O` is reduced to`O_(2)`

Text Solution

Verified by Experts

The correct Answer is:
a

`FetoFe^(2+)+2e` (anode rection)
`O_(2)+2H_(2)O+4eto4OH^(-)` (cathode reaction) The overall reaction is
`2Fe + O_(2) + 2H_(2)O to 2Fe(OH)_(2)`
`Fe(OH)_(2)` may be dehydrated to iron oxide FeO, or further oxidised to `Fe(OH)_(3)` and then dehydrated nto iron rust, `Fe_(2) O_(3)`
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