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The correct decreasing order of first io...

The correct decreasing order of first ionisation enthalpies of five elements of second period is

A

`Be gt B gt C gt N gtF`

B

`N gt F gt C gt B gt Be`

C

`F gt N gt C gt Be gt B`

D

`N gt F gt B gt C gt Be`

Text Solution

Verified by Experts

The correct Answer is:
C

As we move along the period, the atomic size decreases due to increase in nuclear charge. Therefore, it is more difficult to remove electron from an atom. Hence the sequence of first ionization enthalpy in decreasing order is
`FgtNgtCgtBgtBe`
But ionization enthalpy of boron is less as compared to beryllium beacuse first electron in boron is to be removed from p-orbital while in beryllium, is to be removed from s-orbital.
As s-orbital is closer to nucleus in comparison to p-orbital thus energy required to remove an electron from s-orbital is greater.
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DISHA PUBLICATION-CLASSIFICATION OF ELEMENTS AND PERIODICITY IN PROPERTIES-Exercise -1 :Concept Builder (Topic 2)
  1. Which of the following transitions involves maximum amount of energy?

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  2. Ionisation energy decreases down the group due to

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  3. Which one has least ionisation potential?

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  4. Na^(+), Mg^(2+), Al^(3+), and Si^(4+) are isoelectronic ions. Their io...

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  5. Ionic radii are

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  6. Which one of the following ions has the highest value of ionic radius?

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  7. Atomic radil of fluorine and neon in Angstrom units are respectively ...

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  8. The screening effect of inner electrons of an atom can cause

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  9. The second ionization potential of elements is invariably higher than ...

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  10. The pair of elements having approximately equal ionisation potential i...

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  11. Which of the following option is incorrect with respect to ionic radii...

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  12. Which of the following element has maximum, first ionisation potential...

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  13. The radii of F,F^(-),O and O^(-2) are in the order of

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  14. Which of the following has same size?

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  15. The correct decreasing order of first ionisation enthalpies of five el...

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  16. The correct order of second ionisation potential of C, N, O and F is:

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  17. Which of the following arrangements represents the increasing order (s...

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  18. The atomic sizes are not significantly different for the series of ele...

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  19. The correct order of the ionic radii of the ions is

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  20. The decreasing order of the ionization potential of the following elem...

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