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Geometrical isomerism is posible in :...

Geometrical isomerism is posible in :

A

`CH_(3)CH(CH_(3))CH_(2)CH_(2)CH_(3)`

B

`CH_(3)CH=CHCH_(3)`

C

`CH_(3)CH=CH_(2)`

D

`ClH_(2)C-CH_(2)Cl`

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The correct Answer is:
To determine which compound exhibits geometrical isomerism, we need to analyze the options provided based on the criteria for geometrical isomerism, which primarily occurs in alkenes with a carbon-carbon double bond (C=C). Here’s a step-by-step solution: ### Step 1: Understanding Geometrical Isomerism Geometrical isomerism occurs when there is restricted rotation around a double bond, leading to different spatial arrangements of groups attached to the carbon atoms. The two main forms are: - **Cis**: Similar groups are on the same side of the double bond. - **Trans**: Similar groups are on opposite sides of the double bond. ### Step 2: Identify the Presence of a Double Bond Geometrical isomerism is only possible in compounds that contain a carbon-carbon double bond. Therefore, we will look for alkenes (C=C) in the options provided. ### Step 3: Analyze Each Option 1. **Option 1**: No double bond present. - Since there is no double bond, geometrical isomerism is not possible. 2. **Option 2**: Contains a double bond (C=C) with different groups attached. - Example: C=C with H and CH3 on one side and H and CH3 on the other side. - Here, A (CH3) is not equal to B (H), allowing for both cis and trans configurations. Therefore, geometrical isomerism is possible. 3. **Option 3**: Contains a double bond but has two identical groups. - Example: C=C with H and H on one side and CH3 and CH3 on the other side. - Here, A (H) is equal to B (H), which means geometrical isomerism is not possible. 4. **Option 4**: Contains only single bonds. - Since there is no double bond, geometrical isomerism is not possible. ### Conclusion After analyzing all options, **Option 2** is the only compound that can exhibit geometrical isomerism due to the presence of a double bond and different substituents. ### Final Answer **Geometrical isomerism is possible in Option 2.** ---

To determine which compound exhibits geometrical isomerism, we need to analyze the options provided based on the criteria for geometrical isomerism, which primarily occurs in alkenes with a carbon-carbon double bond (C=C). Here’s a step-by-step solution: ### Step 1: Understanding Geometrical Isomerism Geometrical isomerism occurs when there is restricted rotation around a double bond, leading to different spatial arrangements of groups attached to the carbon atoms. The two main forms are: - **Cis**: Similar groups are on the same side of the double bond. - **Trans**: Similar groups are on opposite sides of the double bond. ### Step 2: Identify the Presence of a Double Bond ...
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DISHA PUBLICATION-ORGANIC CHEMISTRY SOME BASIC PRINCIPLES AND TECHNIQUES -Exercise - 2 : Concept Applicator
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  2. Which of the following compound has wrong IUPAC name?

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  3. Structure of the compound whose IUPAC name is 3-ethyl-2-hydroxy-4-meth...

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  4. The IUPAC name of compound

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  5. The IUPAC name of the compound

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  6. The correct IUPAC name of the compound

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  7. Which of the following compounds will show metamerism ?

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  8. Tautomerism will be exhibited by

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  9. Geometrical isomerism is posible in :

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  10. A compound with molecular formula C(7)H(16) shows optical isomerism, t...

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  11. Arrange the (C-H) bonds x,y adn z in decreasing order of their bond de...

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  12. The number of stereoisomers obtained by bromination of trans-2-butane ...

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  13. Which one is a nucleophilic substitution reaction among the following ...

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  14. CH(3)Br +Nu^(Theta) rarr CH(3)-Nu +Br^(Theta) The decreasing order o...

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  15. In the reaction shown below the six membered ring is generated by shi...

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  16. The structures drawn below has four nucleophilic sites , arrange them ...

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  17. The major product of the following is -

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  18. In the given pair compounds in which pair second cpmpound has highter ...

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  19. Arrange in the order of increasing acidic strength :

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  20. Arrange 'a' to 'e' types of H atoms in increasing acidic order.

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