Home
Class 12
CHEMISTRY
Calculate enthalpy change for the change...

Calculate enthalpy change for the change `8S(g)toS_(8)(g)`, given that
`H_(2)S_(2)(g)to2H(g)+2S(g),DeltaH=239.0k"cal mol"^(-1)`
`H_(2)S(g)to2H(g)+S(g),DeltaH=175.0k"cal mol"^(-1)`

A

`+512.0` k cal

B

`-512.0` k cal

C

`508.0` kcal

D

`-508.0` kcal

Text Solution

Verified by Experts

The correct Answer is:
B

`DeltaH_(S-S)+2DeltaH_(H-S)=239" "2DeltaH_(H-S)=175`
Hence `DeltaH_(S-S)=239-175=64kcal "mol"^(-1)`
Then `DeltaH` for `8S(g)toS_(8)` is `8xx(-64)=-512` kcal
Promotional Banner

Topper's Solved these Questions

  • THE SOLID STATE

    DISHA PUBLICATION|Exercise EXERCISE -2 : CONCEPT APPLICATOR|30 Videos

Similar Questions

Explore conceptually related problems

The enthalpy change for the following process are listed below : (a) Cl_(2(g)) rarr 2Cl_((g)), DeltaH=242.3kJ mol^(-1) (b) I_(2(g))rarr 2I_((g)), DeltaH=151.0kJ mol^(-1) (c) ICl_((g)) rarr I_((g))+Cl_((g)), DeltaH=211.3kJ mol^(-1) (d) I_(2(s)) rarr I_(2(g)), DeltaH=62.76kJ mol^(-1) If standard state of iodine and chloride are I_(2(s)) and Cl_(2(g)) , the standard enthalpy of formation for ICl_((g)) is :

Diborane is a potentail rocket fuel which undergoes combusion according to the reaction B_(2)H_(6)(g)+3O_(2)(g)rarrB_(2)O_(3)(s)+3H_(2)O(g) From the following data, calculate the enthalpy change for the combustion of diborane 2B(s)+(3//2)O_(2)(g)rarrB_(2)O_(3)(s) DeltaH= -1273 kJ mol^(-1) H_(2)(g)+(1//2)O_(2)(g)rarrH_(2)O(1) " "Delta H= -286 kJ mol^(-1) H_(2)O(1)rarrH_(2)O(g)" "DeltaH=44 kJ mol^(-1) 2B(s)+3H_(2)(g)rarrB_(2)H_(6)(g)" "Delta H= 36kJ mol^(-1)

Diborane is a potential rocket fuel which undergoes combustion according to the equation B_2H_6(g)+3O_2(g)toB_2O_3(s)+3H_2O(g) Calculate the enthalpy change for the combustion of diborane. Given (i) 2B(s)+3/2O_2(g)toB_2O_3(s), DeltaH=-1273 kj per mol (ii) H_2(g)+1/2O_2(g)toH_2O(I), DeltaH=-286 kj per mol (iii) H_2O(I)toH_2O(g), DeltaH=44 kj per mol (iv) 2B(s)+3H_2(g)toB_2H_6(g), DeltaH=36 kj per mol

Calculate the heat of formation of methane in kcalmol^(-1) using the following thermo chemical reactions C(s)+O_(2)toCO_(2)(g) , DeltaH=-94.2 kcal mol^(-1) H_(2)(g)+1/2O_(2)(g)toH_(2)O(l) , DeltaH=-68.3 kcal mol^(-1) CH_(4)(g)+2O_(2)(g)toCO_(2)(g)+2H_(2)O(l) , DeltaH=-210.8 kcal mol^(-1)

The average O-H Bond energy in H_(2)O with the help of following data : (P) H_(2)O(l)toH_(2)O(g)," "DeltaH=+40.6 kJ mol^(-1) (Q) 2H(g)toH_(2)(g)," "DeltaH=-435.0 kJ mol^(-1) (R ) O_(2)(g)to2O(g)," "DeltaH=+489.6 kJ mol^(-1) (S) 2H_(2)(g)+O_(2)(g)to2H_(2)O(l), " "DeltaH=-571.6 kJ mol^(-1)

DISHA PUBLICATION-THERMODYNAMICS-Exercise
  1. The reaction A to B , DeltaH=+24 kJ//"mole". For the reaction B to C, ...

    Text Solution

    |

  2. Energy required to dissociate 4g of gaseous hydrogen into free gaseous...

    Text Solution

    |

  3. Calculate enthalpy change for the change 8S(g)toS(8)(g), given that ...

    Text Solution

    |

  4. An ideal gas is allowed to expand both reversibly and irreversibly in ...

    Text Solution

    |

  5. On the basic of thermochemical equations (I),(II)and (III), Find out w...

    Text Solution

    |

  6. Following reaction occurring in an automobile 2C(8)H(18)(g)+25O(2)(g) ...

    Text Solution

    |

  7. Enthalpy of CH(4)+(1)/(2)O(2)rarrCH(3)OH is negative. If enthalpy of...

    Text Solution

    |

  8. If the end energies of H-H, Br-Br and H-Br are 433, 192 and 364 kJ mol...

    Text Solution

    |

  9. Calculate the standard enthalpy change (in kJ "mol"^(-1)) for the reac...

    Text Solution

    |

  10. Four grams of graphite is burnt in a bomb calorimeter of heat capacity...

    Text Solution

    |

  11. The standard enthalpy of formation (Delta(f)H^(@)) at 298K for methan...

    Text Solution

    |

  12. At 25^(@)C and 1 bar which one of the following has a non zero DeltaH(...

    Text Solution

    |

  13. The enthalpy of neutralization of NH(4)OH and CH(3)COOH is – 10.5 kcal...

    Text Solution

    |

  14. 250 mLof 0.1 M HCL and 250 mL of 0.1 M KOH, both being at the same tem...

    Text Solution

    |

  15. When 0.2 mole of anhydrous CuSO(4) is dissolved in water, the heat ev...

    Text Solution

    |

  16. The standard heat of formation values of SF(6)(g), S(g), and F(g) are ...

    Text Solution

    |

  17. Calculate the standard enegry change for the reaction: OF(2)(g) +H(2...

    Text Solution

    |

  18. The fat C(57)H(104)O(6)(s), is metabolised via the following reaction ...

    Text Solution

    |

  19. Stearic acid [CH(3)(CH(2))(16)CO(2)H] is a fatty acid the part of fat ...

    Text Solution

    |

  20. An imaginary reaction X rarr Y takes place in three steps X rarr A...

    Text Solution

    |