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Following reaction occurring in an autom...

Following reaction occurring in an automobile `2C_(8)H_(18)(g)+25O_(2)(g) to 16CO_(2)(g)+18H_(2)O(g)`. The sign of `triangleH, triangleS and triangleG` would be-

A

`+,-,+`

B

`-,+,-`

C

`-,+,+`

D

`+,+,-`

Text Solution

Verified by Experts

The correct Answer is:
B

This is combustion reaction, which is always exothermic hence `DeltaH=-ve`
As the no of gaseous molecule are increasing hence entropy increases
Now `DeltaG=DeltaH-TDeltaS`
For a spontaneous reaction
`DeltaG=-ve`
Which is possible in this case as `DeltaH=-ve` and `DeltaS=+ve`.
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