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At temperature 327^(@)C and concentrati...

At temperature `327^(@)C` and concentration C, the osmotic pressure of a solution is P. The same solution at concentration C/2 and a temperature `427^@C` of shows osmotic pressure of 2 atm. The value of P will be :

A

`12/7`

B

`24/7`

C

`6/5`

D

`5/6`

Text Solution

Verified by Experts

The correct Answer is:
B

`piV = CRT`
`pi_1/pi_2 = (C_1T_1)/(C_2T_2)`
`pi_1 = P, pi_2 = 2 atm. C_1 = C, C_2 = C/2`
`T_1 = 600 K, T_2 = 700K`
`P/2 = (2 xx C xx 600)/(C xx 700)`
`P = 24/7`
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