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Vapour pressure of solution containing 2...

Vapour pressure of solution containing 2 mol of liquid A (`P_A^@ = 80` torr) and 3 mol of liquid B (`P_B^@= 100` torr) is 87 torr. We canconclude that

A

there is negative deviation from Raoult's law

B

boiling point is higher than that expected for ideal solution

C

molecular attractions between unlike molecules arestronger than those between like molecules

D

all of these statements are correct

Text Solution

Verified by Experts

The correct Answer is:
D

For ideal solution vapour pressure of solution `=P_A^@x_A + P_B^@x_B`
`80xx2/5 + 100 xx3/5 = 92` torr
Since observed vapour pressure of solution >ideal vapour pressure, the solution shows negative deviation.
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