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The solution containing 4.0gm of a polyv...

The solution containing `4.0gm` of a polyvinyl chloride polymer in `1` litre dioxane was found to have an osmotic pressure `6.0xx10^(-4)`atmosphere at `300K`,the value of R used is `0.082`litre atmosphere`"mole"^(-1)K^(-1)`.The molecular mass of the polymer was found to be

A

`3.0 xx 10^2`

B

`1.6xx10^5`

C

`5.6 xx 10^4`

D

`6.4 xx10^2`

Text Solution

Verified by Experts

The correct Answer is:
B

`pi/V = w/mRT`
`:. 6xx10^(-4) xx1 =4/m xx0.0821 xx300, m = 1.64xx10^5`.
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