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Reaction of diborane with ammonia gives ...

Reaction of diborane with ammonia gives initially

A

`B_(2)H_(6).NH_(3)`

B

Borazole

C

`B_(2)H_(6).3NH_(3)`

D

`[BH_(2)(NH_(3))_(2)]^(+)[BH_(4)]^(-)`

Text Solution

Verified by Experts

The correct Answer is:
D

`B_(2)H_(6) +NH_(3) overset("excess"NH_(3))underset("low temperature") rarr B_(2)H_(6).2NH_(3)`
Diborane with ammonia gives `B_(2)H_(6).2NH_(3)` that is formulated as `[BH_(2)(NH_(3))]^(+)[BH_(4)]^(-)` which when heated to 473 K decomposes to give borazole.
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