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Unlike the other elements of its group c...

Unlike the other elements of its group carbon and silicon does not form `MX_(2)` type molecules because

A

energetically this is not possible.

B

carbon undergoes catenation.

C

it is non-metallie.

D

carbon does not contain d-orbital.

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The correct Answer is:
To understand why carbon and silicon do not form MX₂ type molecules unlike other elements in their group, we can break down the reasoning into several steps: ### Step 1: Identify the Group Carbon and silicon belong to Group 14 of the periodic table, which also includes germanium (Ge), tin (Sn), and lead (Pb). ### Step 2: Understand the Electronic Configuration Carbon (C) has an electronic configuration of 1s² 2s² 2p², while silicon (Si) has 1s² 2s² 2p⁶ 3s² 3p². Both elements have four valence electrons, which allows them to form four covalent bonds. ### Step 3: Analyze Bonding Preferences While carbon and silicon can form various compounds, they primarily prefer to form tetravalent compounds (MX₄) rather than divalent compounds (MX₂). This is due to their ability to form strong covalent bonds with other carbon or silicon atoms (catenation). ### Step 4: Catenation Tendency Catenation is the ability of an element to form chains or rings by bonding with itself. Carbon exhibits a high degree of catenation due to its small atomic size and strong C-C bonds. Silicon also shows catenation but to a lesser extent. This property leads to the formation of stable compounds that are predominantly tetravalent. ### Step 5: Stability of Compounds The stability of MX₂ type compounds decreases for carbon and silicon. Instead, they form more stable tetravalent compounds (MX₄). The other elements in Group 14, such as germanium, tin, and lead, can form MX₂ compounds because their larger atomic size and lower electronegativity allow for different bonding characteristics. ### Step 6: Conclusion Thus, carbon and silicon do not form MX₂ type molecules because it is energetically unfavorable for them to do so. They prefer to form more stable tetravalent compounds due to their unique properties, such as catenation and bond strength. ### Final Answer Carbon and silicon do not form MX₂ type molecules because they prefer to form tetravalent compounds (MX₄) due to their strong catenation ability and the stability of the bonds they can form. ---

To understand why carbon and silicon do not form MX₂ type molecules unlike other elements in their group, we can break down the reasoning into several steps: ### Step 1: Identify the Group Carbon and silicon belong to Group 14 of the periodic table, which also includes germanium (Ge), tin (Sn), and lead (Pb). ### Step 2: Understand the Electronic Configuration Carbon (C) has an electronic configuration of 1s² 2s² 2p², while silicon (Si) has 1s² 2s² 2p⁶ 3s² 3p². Both elements have four valence electrons, which allows them to form four covalent bonds. ...
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DISHA PUBLICATION-The p-Block Elements (Group 13 and Group 14)-Exercise-1: Concept Builder (Topicwise) TOPIC 2: Carbon Family
  1. In silica (SiO(2)), each silicon atom is bonded to

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  2. The inert pair effect is most prominent in

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  3. Unlike the other elements of its group carbon and silicon does not for...

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  4. Which of the following statements about the zeolites is false?

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  5. Lead pipes are not suitable for drinking water because

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  6. Catenation i.e., linking of similar atoms depends on size and electron...

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  7. On controlled hydrolysis and condensation, R(3)SiCl yields

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  8. The most stable +2 oxidation state is exhibited by

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  9. The catenation tendency of C, Si, and Ge is in the order Ge lt Si lt C...

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  10. Ge (II) compounds are powerful reducing agents whereas Pb(IV) compound...

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  11. Which of the following halides is the most stable ?

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  12. PbF(4), PbCl(4) exist but PbBr(4) do not exist because of

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  13. The element that does not form a monoxide is

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  14. Pyrosilicate ion is

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  15. Lead pipes are readily corroded by

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  16. Which halide is least stable and has doubtful existence

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  17. Which does not exist

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  18. The reducing power of divalent species decreases in the order:

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  19. Mg(2)C(3) possess which of the following characteristics?

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  20. Carbon suboxide (C(3)O(2))

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