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When excess of NaOH solution is added in...

When excess of `NaOH` solution is added in potash alum the product is.

A

a bluish precipitate

B

clear solution

C

white precipitate

D

greenish precipitate

Text Solution

Verified by Experts

The correct Answer is:
B

Potash alum is `K_(2)SO_(4)Al_(2)(SO_(4))_(3) cdot 24H_(2)O`.
`Al_(2)(SO_(4))_(3)` reacts with NaOH to form `NaAlO_(2)` which is soluble. `K_(2)SO_(4) and Na_(2)SO_(4)` are also soluble and thus a clear solution is obtained in water.
`Al_(2)(SO_(4))_(3)+6NaOH rarr 2 Al(OH)_(3) +3Na_(2)SO_(4)`
`Al(OH)_(3)+NaOH rarr underset("Soluble")NaAlO_(2) +2H_(2)O`
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