Home
Class 12
CHEMISTRY
The gas evolved on heating CaF(2) and Si...

The gas evolved on heating `CaF_(2) and SiO_(2)` with concentrated `H_(2)SO_(4)`, on hydrolysis gives a white gelatinous precipitate.
The precipitate is :

A

hydrofluorosilicic acid

B

silica gel

C

silicic acid

D

calciumfuorosilicate

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the reactions that occur when calcium fluoride (CaF₂) and silicon dioxide (SiO₂) are heated with concentrated sulfuric acid (H₂SO₄) and then undergo hydrolysis. ### Step-by-Step Solution: 1. **Identify the Initial Reaction**: When calcium fluoride (CaF₂) is heated with concentrated sulfuric acid (H₂SO₄), it reacts to produce hydrogen fluoride (HF) and calcium sulfate (CaSO₄). \[ \text{CaF}_2 + \text{H}_2\text{SO}_4 \rightarrow \text{HF} + \text{CaSO}_4 \] 2. **Identify the Second Reaction**: The hydrogen fluoride gas produced can then react with silicon dioxide (SiO₂). This reaction forms silicon tetrafluoride (SiF₄) and water (H₂O). \[ \text{HF} + \text{SiO}_2 \rightarrow \text{SiF}_4 + \text{H}_2\text{O} \] 3. **Hydrolysis of Silicon Tetrafluoride**: The silicon tetrafluoride (SiF₄) gas can then undergo hydrolysis when it comes into contact with water. This reaction produces hydrofluorosilicic acid (H₂SiF₆) and silica (SiO₂), which is a white gelatinous precipitate. \[ \text{SiF}_4 + 2 \text{H}_2\text{O} \rightarrow \text{H}_2\text{SiF}_6 + \text{SiO}_2 \] 4. **Conclusion**: The white gelatinous precipitate formed during hydrolysis is silica (SiO₂). Therefore, the answer to the question is that the precipitate is **silica**. ### Final Answer: The white gelatinous precipitate is **silica (SiO₂)**.

To solve the question, we need to analyze the reactions that occur when calcium fluoride (CaF₂) and silicon dioxide (SiO₂) are heated with concentrated sulfuric acid (H₂SO₄) and then undergo hydrolysis. ### Step-by-Step Solution: 1. **Identify the Initial Reaction**: When calcium fluoride (CaF₂) is heated with concentrated sulfuric acid (H₂SO₄), it reacts to produce hydrogen fluoride (HF) and calcium sulfate (CaSO₄). \[ \text{CaF}_2 + \text{H}_2\text{SO}_4 \rightarrow \text{HF} + \text{CaSO}_4 ...
Promotional Banner

Topper's Solved these Questions

  • The p-Block Elements (Group 13 and Group 14)

    DISHA PUBLICATION|Exercise Exercise-1: Concept Builder (Topicwise) TOPIC 2: Carbon Family|28 Videos
  • THE D- AND F- BLOCK ELEMENTS

    DISHA PUBLICATION|Exercise EXERCISE - 2 CONCEPT APPLICATOR|30 Videos
  • THE P-BLOCK ELEMENTS (GROUP 15, 16, 17 & 18)

    DISHA PUBLICATION|Exercise Exercise|110 Videos

Similar Questions

Explore conceptually related problems

CaF_(2)+H_(2)SO_(4) to

Formic acid (HCOOH) on heating with concentrated H_(2)SO_(4) gives

A white crystalline compound (X) swells open heating and gives violet-coloured flame. Its aqueous solution gives the following reactions : (a) A white precipitate is formed, with BaCl_(2) in presence of HCl . (b) When treated with excess of NH_(4) OH , it gives white gelatinous precipitate. the white precipitate dissolves in NaOH and reappears on boiling with concentrated solution of NH_(4) Cl . ( c) It gives yellow precipitate with cobaltinitrite solution. Identify (X) and explain the reaction at steps a, b and c .

Cu^(2+) ions give white precipitate with :

Ethylene glyco, HOCH_(2)CH_(2)OH, on heating with concentrated H_(2)SO_(4) gives mainly.

A white crystalline substance dissolves in water.On passing H_(2)S in this solution, a black precipitate is obtained.The black precipitate dissolves completely in hot HNO_(3) .On adding a few drops of concentrated H_(2)SO_(4) , a white precipitate is obtained.This precipitate is that of

Which of the following salt on heating with concentrated H_(2)SO_(4) , coloured vapours do not evolve?

A solution of white solid (A) gave white precipitate (B) with water. On treatment with HCl, the ppt. B produced A. The solution of A gives black precipitate (C ) on reacting with sodium stanite and NaOH. The compound A gives a colourless gas (D) with concentrated H_(2)SO_(4) . The gas is soluble in water and its aqueous solution produce with it precipitate with Hg_(2)(NO_(3))_(2) but no precipitate with Hg(NO_(3))_(2) . Identify (A) to (D) and write the chemical reactions involved.

DISHA PUBLICATION-The p-Block Elements (Group 13 and Group 14)-Exercise-2: Concept Applicator
  1. The number of isomers possible for disubstituted borazine, B(3)N(3)H(4...

    Text Solution

    |

  2. How can the following reaction be made to proceed in forward direction...

    Text Solution

    |

  3. When excess of NaOH solution is added in potash alum the product is.

    Text Solution

    |

  4. The structure of boron nitride resembles that of

    Text Solution

    |

  5. To a piece of charcoal, sulphuric acid is added. Then:

    Text Solution

    |

  6. Carbon and silicon belong to group IV. The maximum coordination number...

    Text Solution

    |

  7. Soldiers of Napolean army while at alps during freezing winter suffere...

    Text Solution

    |

  8. Which one of the following allotropic forms of carbon is isomorphous w...

    Text Solution

    |

  9. The structure and hybridization of Si(CH(3))(4) is

    Text Solution

    |

  10. A solid element (symbol Y) conducts electricity and forms two chloride...

    Text Solution

    |

  11. On addition of excess of sodium hydroxide solution to stannous chlorid...

    Text Solution

    |

  12. Name the gas that can readily decolourise acidified KMnO(4) solution:

    Text Solution

    |

  13. Identify the incorrect statement

    Text Solution

    |

  14. The gas evolved on heating CaF(2) and SiO(2) with concentrated H(2)SO(...

    Text Solution

    |

  15. In silicon dioxide :

    Text Solution

    |

  16. Of the following types of glass, the one with the smallest coefficient...

    Text Solution

    |

  17. Number and type of bonds between two carbon atoms in CaC(2) are :

    Text Solution

    |

  18. The gas A is bubbled through lime water , a while precipitate is forme...

    Text Solution

    |

  19. The straight chain polymer (silicones) is formed by

    Text Solution

    |

  20. In silicon dioxide

    Text Solution

    |