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K(1) & K(2) for oxalic acid are 6.5 xx 1...

`K_(1)` & `K_(2)` for oxalic acid are `6.5 xx 10^(-2)` and `6.1 xx 10^(-5)` respectively . What will be the `[OH^(-)]` in a `0.01 M` solution of sodium oxalate

A

`9.6xx10^(-6)`

B

`1.4xx10^(-1)`

C

`1.3xx10^(-6)`

D

`1.3xx10^(-8)`

Text Solution

Verified by Experts

The correct Answer is:
C

The hydrolysis of `C_(2)O_(4)^(2-)` is as follows
`C_(2)O_(4)^(2-)+H_(2)OhArrHC_(2)O_(4)^(-)+H^(-)`
`K_(h)=(K_(w))/(K_(2))=(1.0xx10^(-14))/(6.0xx10^(-5))=(x^(2))/(0.01)`
`:.x=1.3xx10^(-6)`
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DISHA PUBLICATION-EQUILIBRIUM-Exercise-2 : Concept Applicator
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  4. Which of the following will decrease the pH of a 50 ml solution of 0.0...

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