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Phthalic acid reacts with resorcinol in ...

Phthalic acid reacts with resorcinol in the presence of concentrated `H_(2)SO_(4)` to give:

A

Phenolphthalein

B

Alizarin

C

Coumarin

D

Fluorescein

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The correct Answer is:
To solve the problem of what product is formed when phthalic acid reacts with resorcinol in the presence of concentrated sulfuric acid, we can follow these steps: ### Step 1: Understand the Reactants Phthalic acid (C₆H₄(COOH)₂) is a dicarboxylic acid with two carboxylic acid groups attached to a benzene ring. Resorcinol (C₆H₄(OH)₂) is a dihydroxybenzene with two hydroxyl groups on the benzene ring. ### Step 2: Reaction of Phthalic Acid with Concentrated Sulfuric Acid When phthalic acid is treated with concentrated sulfuric acid, it undergoes dehydration to form phthalic anhydride (C₈H₄O₃). This reaction involves the loss of water from the carboxylic acid groups. **Reaction:** \[ \text{Phthalic Acid} \xrightarrow{H_2SO_4} \text{Phthalic Anhydride} + H_2O \] ### Step 3: Reaction of Phthalic Anhydride with Resorcinol Phthalic anhydride can react with resorcinol. In this reaction, the hydroxyl groups of resorcinol will attack the carbonyl carbon of phthalic anhydride, leading to the formation of a new compound. **Mechanism:** 1. The nucleophilic hydroxyl group of resorcinol attacks the electrophilic carbon of the carbonyl group in phthalic anhydride. 2. This results in the opening of the anhydride ring and formation of a new compound. ### Step 4: Structure of the Product The product formed from the reaction of phthalic anhydride with resorcinol is fluorescein. Fluorescein has a structure that consists of a central xanthene core with hydroxyl groups in the ortho and para positions relative to each other. **Final Product:** The final product is fluorescein (C₁₃H₈O₃), which is a fluorescent dye. ### Conclusion Thus, the reaction of phthalic acid with resorcinol in the presence of concentrated sulfuric acid yields fluorescein. ### Summary of Steps: 1. Identify the reactants: phthalic acid and resorcinol. 2. Understand the conversion of phthalic acid to phthalic anhydride using concentrated sulfuric acid. 3. Describe the reaction of phthalic anhydride with resorcinol. 4. Conclude that the product is fluorescein. ---

To solve the problem of what product is formed when phthalic acid reacts with resorcinol in the presence of concentrated sulfuric acid, we can follow these steps: ### Step 1: Understand the Reactants Phthalic acid (C₆H₄(COOH)₂) is a dicarboxylic acid with two carboxylic acid groups attached to a benzene ring. Resorcinol (C₆H₄(OH)₂) is a dihydroxybenzene with two hydroxyl groups on the benzene ring. ### Step 2: Reaction of Phthalic Acid with Concentrated Sulfuric Acid When phthalic acid is treated with concentrated sulfuric acid, it undergoes dehydration to form phthalic anhydride (C₈H₄O₃). This reaction involves the loss of water from the carboxylic acid groups. ...
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DISHA PUBLICATION-ALDEHYDES, KETONES AND CARBOXYLIC ACIDS-Exercise - 2 : Concept Applicator
  1. Phthalic acid reacts with resorcinol in the presence of concentrated H...

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  2. Product (B) is :

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  3. overset(HO^(-))underset(Delta)rarr underset((72%))((C ))," Product (C ...

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  4. (Q) overset(BOH)underset(Delta)rarr Ph-CH(2)-OH+Ph-CO(2) (R ) overse...

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  5. The respectively compounds A and B are

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  6. From the ozonolysis products, the two isomers A and B can be distingui...

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  7. Above compounds can be differentiated by following reagent :

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  8. Product (B) in this reaction is :

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  9. The product formed in the reaction is -

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  10. (A)underset("dil."H(2)SO(4))overset(HgSO(4))(to)(B)overset(LiAlH(4))(t...

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  11. overset(P C C)rarr (C )overset(HO^(-))underset(Delta)rarr (D ) What ...

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  12. Identify correct combination :

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  13. Which of the following is the product of aldol condensation?

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  14. Which of the following reagent(s) used for the conversion?

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  15. Which of the following reaction with (CH(3)CH(2))(2)NH to give the com...

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  16. CH(3)-overset(O)overset(||)C-CH(2)-CH(3)+CH(3)MgBrrarr X overset(H(3)O...

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  17. C(6)H(5)overset(O)overset(||)C CH(3)+C(6)H(5)CHO overset(H^(+))rarr C(...

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  18. The structure of the compound Y in the following reactions should be

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  19. Reaction of cyclohexanone with dimethylamine in the presence of cataly...

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  20. The increasing order of the rate of HCN addition to compound A-D is ...

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  21. Which of the following statement is incorrect about the reaction of am...

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