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Which carbon atoms are most susceptible ...

Which carbon atoms are most susceptible to nucleophilic attack?
`underset((A))(CH_(3))-underset((B))(CH)=underset(C )(CH)-overset(O)overset(||)underset(D)C-CH_(3)`

A

A and B

B

B and C

C

B and D

D

A and D

Text Solution

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The correct Answer is:
To determine which carbon atoms are most susceptible to nucleophilic attack in the given structure, we need to analyze the molecular structure and identify the electrophilic centers. ### Step-by-Step Solution: 1. **Identify the Structure**: The structure given is: ``` CH3 - CH = CH - C(=O) - CH3 ``` Here, we have a carbon chain with a carbonyl group (C=O) present. 2. **Recognize Electrophilic Centers**: In organic chemistry, nucleophiles are attracted to electrophilic centers, which are typically carbon atoms bonded to electronegative atoms (like oxygen) or involved in double bonds. The carbonyl carbon (C=O) is a prime electrophilic site due to the polarization of the C=O bond. 3. **Analyze Each Carbon**: - **Carbon A (CH3)**: This carbon is not electrophilic as it is bonded to hydrogens and is part of a methyl group. - **Carbon B (CH)**: This carbon is part of a double bond (alkene) and can be somewhat electrophilic, but not as much as the carbonyl carbon. - **Carbon C (CH)**: This carbon is also part of a double bond and is adjacent to the carbonyl carbon, making it somewhat electrophilic. - **Carbon D (C=O)**: This carbon is bonded to an oxygen atom with a double bond, making it highly electrophilic due to the significant polarization of the bond. 4. **Determine Susceptibility**: The carbon atom that is most susceptible to nucleophilic attack is the carbonyl carbon (Carbon D) because it has a partial positive charge due to the electronegativity of the oxygen atom. 5. **Conclusion**: Therefore, the carbon atom that is most susceptible to nucleophilic attack is **Carbon D** (the carbon in the carbonyl group). ### Final Answer: The carbon atom most susceptible to nucleophilic attack is **Carbon D** (C=O).

To determine which carbon atoms are most susceptible to nucleophilic attack in the given structure, we need to analyze the molecular structure and identify the electrophilic centers. ### Step-by-Step Solution: 1. **Identify the Structure**: The structure given is: ``` CH3 - CH = CH - C(=O) - CH3 ``` ...
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