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CH(3)COCH(2)Cl overset(OH^(-),Cl(2))rarr...

`CH_(3)COCH_(2)Cl overset(OH^(-),Cl_(2))rarr " Product P "` is

A

`ClCH_(2)COCH_(2)Cl`

B

`CH_(3)COCHCl_(2)`

C

both a and b

D

`ClCH_(2)COOH+CH_(3)Cl`

Text Solution

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The correct Answer is:
To solve the question, we need to analyze the reaction of CH₃COCH₂Cl with OH⁻ and Cl₂ step by step. ### Step 1: Identify the Reactants The reactants are: - CH₃COCH₂Cl (which is 2-chloropropan-2-one) - OH⁻ (hydroxide ion) - Cl₂ (chlorine gas) ### Step 2: Role of OH⁻ The hydroxide ion (OH⁻) acts as a base. Its primary role in this reaction is to abstract a proton (H⁺) from the molecule. We need to identify where the acidic protons are located in CH₃COCH₂Cl. ### Step 3: Identify Acidic Protons In CH₃COCH₂Cl, there are two potential acidic protons: 1. The proton on the CH₃ group (methyl group). 2. The proton on the CH₂ group (methylene group). ### Step 4: Proton Abstraction When OH⁻ abstracts a proton, it can do so from either of the two positions. However, the proton on the CH₂ group is more acidic due to the electron-withdrawing effect of the carbonyl (C=O) group. Thus, OH⁻ will preferentially abstract the proton from the CH₂ group. After the abstraction, we get: - CH₃C(=O)CH₂⁻ (a carbanion is formed at the CH₂ position) ### Step 5: Formation of the Carbanion The carbanion formed (CH₃C(=O)CH₂⁻) is stabilized by the adjacent carbonyl group (C=O), which can help stabilize the negative charge through resonance. ### Step 6: Reaction with Cl₂ Now, the carbanion (CH₃C(=O)CH₂⁻) will react with Cl₂. The negative charge on the carbanion will attack one of the chlorine atoms in Cl₂, leading to the substitution of the chlorine atom. ### Step 7: Product Formation The chlorine atom that is attacked will bond with the carbon atom that originally had the negative charge, resulting in the formation of: - CH₃C(=O)CHCl₂ (dichloro compound) ### Final Product Thus, the product P formed from the reaction is CH₃C(=O)CHCl₂. ### Summary of Steps: 1. Identify the reactants. 2. Recognize the role of OH⁻ as a base. 3. Identify the acidic protons in the molecule. 4. Determine which proton is abstracted by OH⁻. 5. Form the carbanion and stabilize it. 6. React the carbanion with Cl₂. 7. Conclude with the final product.

To solve the question, we need to analyze the reaction of CH₃COCH₂Cl with OH⁻ and Cl₂ step by step. ### Step 1: Identify the Reactants The reactants are: - CH₃COCH₂Cl (which is 2-chloropropan-2-one) - OH⁻ (hydroxide ion) - Cl₂ (chlorine gas) ...
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