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(CH(3))(2)C=CHCOCH(3) can be oxidised to...

`(CH_(3))_(2)C=CHCOCH_(3)` can be oxidised to `(CH_(3))_(2) C=CHCOOH` by

A

Chromic acid

B

`NaOI`

C

`Cu" at "300^(@)C`

D

`KMnO_(4)`

Text Solution

Verified by Experts

The correct Answer is:
B

Chromic acid and `KMnO_(4)` will cleave the molecules at the site of double bond while Cu at `300^(@)C` cannot oxidise `COCH_(3)` to `COOH`. The only reagent suitable for thic conversion is `NaOH` or `NaOH+I_(2)` (iodoform test):
`(CH_(3))_(2)C=CHCOCH_(3) overset(NaOH)rarr (CH_(3))_(2)C=CHCOOH+CHI_(3)`.
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DISHA PUBLICATION-ALDEHYDES, KETONES AND CARBOXYLIC ACIDS-Exercise - 1 : Concept Builder (Topicwise) (TOPIC 2 : Properties of Carbonyl Compounds)
  1. CH(3)COCH(2)Cl overset(OH^(-),Cl(2))rarr " Product P " is

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  2. Formalin is an aqueous solution of

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  3. (CH(3))(2)C=CHCOCH(3) can be oxidised to (CH(3))(2) C=CHCOOH by

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  4. Aldehydes and ketones will not form crystalline derivatives with

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  5. Which of the following compounds will undergo self aldol condensation ...

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  6. Appropriate reducing agent for the following conversion is - CH(2)=C...

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  7. Which of the following is a disproportionation reaction ?

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  8. The reactant ( X) in the reaction, ( X) underset( (CH(3)CO)(2)O) ove...

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  9. underset((A))(C(16)H(16))overset(O(3))rarr underset(C(8)H(8)O)((B))ove...

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  10. Ph-overset(O)overset(||)(C)-OH overset(SOCl(2))(to)(A) underset(Pd- Ba...

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  11. Arrange the followoing carbonyl compounds in decreasing order of their...

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  12. In the above reaction, product (B) is :

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  13. Which of the major product of the following reaction? CH(3)-overset(O...

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  14. Arrange the following compounds in order of their reactivity toward Li...

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  15. Which one of the following compounds will be most readily dehydrated?

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  16. Acetone is treated with excess of ethanol in the presence of hydrochlo...

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  17. Consider the reaction RCHO + NH(2)NH(2) rarr R - CH = N NH(2) What...

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  18. Which of the following compounds will give a yellow precipitate with i...

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  19. The order of stability of the following tautomeric compounds is (i)....

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  20. Which one is most reactive towards nucleophilic addition reaction?

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